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生物质木质素沸石分子筛催化转化
BIOMASSSOURCESFUELSANDCHEMICALSCatalyticProcessingofBiomassCATALYTIC
PROCESSES
GasificationSyn-gasH2+COFastPyrolysisLiquefactionBio-OilsSugarsAcidsAldehydesAromaticsWGSR?HydrogenMethanol?GasolineFischer-Tropsch?DieselFermentation?EthanolDeoxygenationHydrogenationZeoliteUpgradingEmulsionsCondensationSolvolysisHydrolysisLigningC5sugarsC6sugarsFermentationto
EthanolandButanolHydrogenationZeoliteUpgradingAqueousPhase ReformingtoH2CondensationsugarsSwitchgrasscellulose,hemicellulose,lignin
GasificationSyn-gasH2+COFastPyrolysisLiquefactionBio-OilsSugarsAcidsAldehydesAromaticsWGSR?HydrogenMethanol?GasolineFischer-Tropsch?DieselFermentation?EthanolDeoxygenationHydrogenationZeoliteUpgradingEmulsionsCondensationSolvolysisHydrolysisLigningC5sugarsC6sugarsFermentationto
EthanolandButanolHydrogenationZeoliteUpgradingAqueousPhase ReformingtoH2CondensationsugarsSwitchgrasscellulose,hemicellulose,lignin
Thermo-chemicalbiomassconversionBiomassCelluloseLigninPhenolicsAceticacidAcetolAcetonefurfuralPyrolysisAcids,Ketones,FuransEsters,Sugars,Dehydrosugars,Shortaldehydes,PhenoliccompoundsBio-oil
Propertiesofbio-oilandfuelsWhy“conventional”pyrolysisoilvalorizationneedsadditionalmolecularengineeringeffortsPropertiesPyrol.OilGasol.DieselFuelOilEngineimpactsDensitykgm-31220723854963MustfulfillspecificationC(Wt.%)48.584.586.387.2HeatpowerH(wt.%)6.413.112.911.6HeatpowerO(wt.%)40.50.00.00.0HelptheinternalcombustionS(Wt.%)~00.00010.0011SpecificationViscosityCST130.122.5351AtomizationinthechamberFlashPointoC664570100HClossesandpollutionPourPointoC-30-20-2021OperationincoldareasAsh(wt.%)0.130.0010.010.03IncylinderdepositionWater(wt.%)20.50.10.10.1Atomization–emissionsCetane#?--42--PerformanceandemissionsOctane#?80----PerformanceWatersolub.soluble0.1-1Pollutioninspills-degradationBiodegradationhighLowmediumLowSpills–stor
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