20种氨基酸残基核磁共振谱的化学位移.docxVIP

20种氨基酸残基在无规卷曲肽段中的1H化学位移

残基

NH

αH

βH

其它

Gly

8.39

3.97

Ala

8.25

4.35

1.39

Val

8.44

4.18

2.13

γCH30.970.94

Ile

8.19

4.23

1.90

γCH21.48,1.19;γCH30.95;δCH30.89

Leu

8.42

4.38

1.65,1.65

γH1.64;δCH30.94,0.90

Pro

4.44

2.28,2.02

γCH22.03,2.03;δCH33.68,3.65

Ser

8.38

4.50

3.88,3.88

Thr

8.24

4.35

4.22

γCH31.23

Asp

8.41

4.76

2.84,2.75

Glu

8.37

4.29

2.09,1.97

γCH22.31,2.28

Lys

8.41

4.36

1.85,1.76

γCH21.45,1.45;δCH21.70,1.70;εCH23.02,3.02;εNH3+7.52

Arg

8.27

4.38

1.89,1.79

γCH21.70,1.70;δCH23.32,3.32,NH7.17,6.62

Asn

8.75

4.75

2.83,2.75

γNH27.59,6.91

Gln

8.41

4.37

2.13,2.01

γCH22.38,2.38;δNH26.87,7.59

Met

8.42

4.52

2.15,2.01

γCH22.38,2.38;δCH22.13

Cys

8.31

4.69

3.28,2.96

Trp

8.09

4.70

3.32,3.19

2H7.24;4H7.65;5H7.17;6H7.24;7H7.50;NH10.22

Phe

8.23

4.66

3.22,2.99

2,6H7.30;3,5H7.39;4H7.34

Tyr

8.18

4.60

3.13,2.92

2,6H7.15;3,5H6.86

His

8.41

4.63

3.26,3.20

2H8.12;4H7.14

20种氨基酸残基在无规卷曲肽段中的13C化学位移

残基

C=O

Cα

Cβ

其他

Ala

177.8

52.5

19.1

Cys还原

174.6

58.2

29.0

Cys氧化

174.6

55.4

41.1

Asp

176.3

54.2

41.1

γCO180.0

Glu

176.6

56.6

29.9

γCH235.6δCO183.4

Phe

175.8

57.7

39.6

1C138.9;2,6CH131.9;3,5CH131.54CH129.9

Gly

174.9

45.1

His

174.1

55.0

29.0

2CH136.2,4CH120.1,5C131.1

Ile

176.4

61.1

38.8

γCH227.2;γCH317.4;δCH312.9

Lys

176.6

56.2

33.1

γCH224.7;δCH229.0;εCH241.9

Leu

177.6

55.1

42.4

γCH26.9;δCH324.9,23.3

Met

176.3

55.4

32.9

γCH232.0;εCH316.9

Asn

175.2

53.1

38.9

γCO177.2

Pro

177.3

63.3

32.1

γCH227.2;δCH249.8

Gln

176.0

55.7

29.4

γCH233.7;δCO180.5

Arg

176.3

56.0

30.9

γCH227.1;δCH243.3;εC159.5

Ser

174.6

58.3

63.8

Thr

174.7

61.8

69.8

γCH321.5

Val

176.3

62.2

32.9

γCH321.1;20.3

Trp

176.1

57.5

29.6

2CH127.4;3C111.2;4CH122.2;5CH124.8;6CH121.0;7CH114.7;8C138.7;9C129.5

Tyr

175.9

57.9

38.8

1C130.6;2,6CH133.3;3，5C