- 1、本文档共118页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
Ch3Sputtering/溅射;引子-Whatissputtering?;
①荷能粒子为几十个电子伏特的粒子
--说明入射粒子的能量范围
②入射粒子或粒子束,一般意义上的溅射就是指离子溅射。
③出射原子靠近表面;;3.1、等离子体-Howcansputteringhappen?;6;7;2、Howisaplasmacreated?;anelectricfieldisintroducedthatacceleratesthefreeelectrons
theacceleratedfreeelectronscollidewithneutralgasmolecules
followingthecollision,oneofthreethingscanhappen:
a.dissociation
b.ionization
c.excitation;3、Chargeofplasma;11;;等离子体鞘层:;;分解-Dissociation:
Gasmoleculesarebrokendownintosmallerfragmentscalled“FreeRadicals”:
M+e-=M1+M2+e-
Freeradicalsarehigh-energychemicalspecies.
Althoughtheyareelectricallyneutral,theyareunstable.
Theyreadilyreactwithothersubstancesinordertoachieveamorestableconfiguration.;Dissociation:
Intheexampleshown,thefreeradicalClisgenerated.ThestablestateofchlorineisCl2.
SinceCl(byitself)is unstable,itreadily
reactswithaluminum
asfollows:
Al(s)+3Cl(g)?AlCl3(g)
Thisisanaluminum
etchprocess.;Dissociation:
ThereverseprocessofDissociationiscalledRecombination.
Iftheyarenot“usedup”inotherchemicalreactions,thefreeradicalswillspontaneouslyrecombinetoresumetheirmorestablestates:
CCl3+Cl?CCl4
FreeRadicalsaretheusefulproductsofaplasmathatareusedin:
PlasmaEnhancedChemicalVaporDeposition(PECVD)
outcomeofthechemicalreactionisasolid
PlasmaEtchingandPlasmaCleaning
outcomeofthechemicalreactionisavapor;Electron(s)areknockedloosefromaneutralatomormolecule
M+e-=M++2e-
Theresultantpositively chargedparticlesare called“ions.”
Sincetheycarryan electriccharge,ions canbemanipulatedbyan electricfield.;ImpactIonization:
Intheequationonthepreviousslide,itshouldbenotedthattherearenowTWOfreeelectrons, followingthecollision.
Thisdoublesthe
文档评论(0)