分析化学英文课件CH07 Precipitation titration and gravimetry 1208.ppt

Chapter7-PrecipitationEquilibrium,TitrationandGravimetry1

OutlinePrecipitationequilibriumPrecipitationtitrationPrecipitationgravimetry2

Precipitationequilibriumandsolubilitysolubility-productconstant/solubilityproduct3

Solubilityinpurewater4

Electrolytesolution:salteffectconcentrationsolubilityproductconstantionicstrengthHowionswithdifferentchargesinfluence?5

Electrolytesolution:commonioneffectI=0.1amountofBaSO4in250mlsolutionifnointerferingionssolubility6

solutionwithexcessiveBa2+withconcentrationof0.01mol/LsolubilityamountofBaSO4in250mlsolution7

DependentofpHandotherligandsSidereactionswiththeionsReducetheeffectiveactivityIncreasethesolubility8

conditionalsolubility-productconstant9

CalculatethesolubilityofCaC2O4undergivensolution,asisknownthatforoxalicacid,pKavaluesas1.1and4.0respectively,andpurewaterinpH1.0HClsolutionapH4.0solutionwithanalyticalconcentrationofnon-precipitatedoxalateof0.1mol/L10

CalculatesolubilityofMnSinpurewater,Validityoftheassumption?11

CalculatethesolubilityofPbC2O4atpH4.0whentheanalyticalconcentrationofoxalateis0.2mol/LandthatofEDTA(Y)notbindingwithPb2+is0.01mol/L.ItisknownthatKsp(PbC2O4)=10-9.7andlgK(PbY)=18.012

morethanoneeffectoccursatthesametimeTheeffectofCl-concentrationonthesolubilityofAgCl13

PrecipitationtitrationRequirements(limitedapplications)ReactionratehighenoughSpecificstoichiometrySolubilitysmallenoughLessadsorption,smallerrorsProduceasubstanceoflimitedsolubility14

ConstructionoftitrationcurveTitrate20.00mL0.1000mol/LNaClwith0.1000mol/LAgNO30.1%pre-SPRightatSP0.1%post-SP15

Titrationcurvefor0.1000mol/LhalidesusingAgNO3atthesameconcentration16

ApplicationofprecipitationtitrationMohrmethod:K2CrO4Volhardmethod:NH4Fe(SO4)2Fajansmethod:adsorptionindicatorArgentometry:classifiedbyendpointindicator