年产60万吨年煤制乙二醇的初步工艺设计（修改）.docxVIP

年产60万吨煤制乙二醇的初步工艺设计

摘要

本项目针对我国乙二醇供需矛盾，完成了年产60万吨煤制乙二醇工厂的工艺设计。以煤炭间接液化项目副产的合成气（CO、H?）为原料，采用酯化-羰化-加氢技术路线，通过草酸二甲酯（DMO）合成、羰化反应、加氢制乙二醇及联产碳酸二甲酯（DMC）的工艺流程，实现了煤基资源的高效转化。设计重点优化了反应工段催化剂体系（引入La助催化剂提升钯基催化剂稳定性）、创新分离技术（高压精馏解决DMO固化难题）、构建驰放气循环与废酸再生系统，并完成全流程模拟与关键设备（反应精馏塔、萃取塔等）参数优化。结果表明：乙二醇纯度达99.9%，DMC纯度99.8%，原料利用率提升15%，蒸汽能耗降低25%，废气减排30%，设备国产化率达95%。研究为煤基乙二醇工业化生产提供了理论依据和设计参考。

关键词：煤制乙二醇；工艺优化；草酸二甲酯加氢；节能降耗

Abstract

Thisprojectaimstoaddressthesupply-demandimbalanceofethyleneglycolinChinaandhascompletedtheprocessdesignofacoaltoethyleneglycolfactorywithanannualoutputof600000tons.Usingthesynthesisgas(CO,H?)producedasabyproductofthecoalindirectliquefactionprojectasrawmaterial,theesterificationcarbonylationhydrogenationtechnologyroutewasadoptedtoachieveefficientconversionofcoalbasedresourcesthroughtheprocessofsynthesizingdimethyloxalate(DMO),carbonylationreaction,hydrogenationtoproduceethyleneglycol,andcoproducingdimethylcarbonate(DMC).Thedesignfocusesonoptimizingthecatalystsysteminthereactionsection(introducingLacocatalysttoenhancethestabilityofpalladiumbasedcatalyst),innovatingseparationtechnology(solvingtheproblemofDMOsolidificationthroughhigh-pressuredistillation),constructingaventinggascirculationandwasteacidregenerationsystem,andcompletingthefullprocesssimulationandparameteroptimizationofkeyequipment(reactiondistillationtower,extractiontower,etc.).Theresultsshowedthatthepurityofethyleneglycolreached99.9%,thepurityofDMCwas99.8%,theutilizationrateofrawmaterialswasincreasedby15%,thesteamenergyconsumptionwasreducedby25%,theexhaustgaswasreducedby30%,andthedomesticationrateofequipmentreached95%.Theresearchprovidestheoreticalbasisanddesignreferencefortheindustrialproductionofcoalbasedethyleneglycol.

Keywords:coaltoethyleneglycol;Processoptimization;Hydrogenationofdimet