(2.4.7)--电离能和亲和能.pptVIP

2.4.2Theionizationenergyandtheaffinityenergy

Theminimumenergyrequiredtoremoveanelectronfromoneofitsorbitals(inthegasphase).ThefirstionizationenergyThesecondionizationenergyI.Ionizationenergy:

PeriodicTrendsinIonizationPotentials

II.EstimationofionizationenergyExample:C?C+,1s22s22p2?1s22s22p1I1=?E=E(C+)-E(C)

Example:Fe+forlackingofaKelectron,Z=26Electronconfiguration:1s12s22p63s23p64s23d6(1s1)(2s22p6)(3s23p6)(3d6)(4s2)1s:26–0*0.30=26.002s,2p:26–7*0.35–1*0.85=22.703s,3p:26–7*0.35–8*0.85–1*1.0