2025年MCAT化学专项训练预测卷.docxVIP

2025年MCAT化学专项训练预测卷

考试时间：______分钟总分：______分姓名：______

PartA:

1.Considerthefollowingmolecularspecies:H2S,CH4,andCO2.Arrangethesemoleculesinorderofincreasingbondanglearoundthecentralatom,andjustifyyourrankingbasedonelectronpairrepulsiontheory.

2.A0.250Msolutionofhydrochloricacid(HCl)ismixedwitha0.150Msolutionofsodiumacetate(CH3COONa).CalculatetheexpectedpHoftheresultingbuffersolution.Providetherelevantequilibriumexpressionandkeycalculations.

3.Forthereaction2NO(g)+O2(g)→2NO2(g),therateofformationofNO2is0.035M/s.WhatistherateofconsumptionofO2undertheseconditions?Explainyourreasoning.

4.Definestandardenthalpyofformation(?H°f).Usingstandardenthalpyvalues(assume?H°f[CO2(g)]=-393.5kJ/mol,?H°f[H2O(l)]=-285.8kJ/mol,?H°f[C(graphite)]=0kJ/mol,?H°f[H2(g)]=0kJ/mol),calculatethestandardenthalpychangeforthecombustionofethanol(C2H5OH(l)):

C2H5OH(l)+3O2(g)→2CO2(g)+3H2O(l)

5.Explaintheconceptofhybridizationasitappliestothecentralcarbonatominethene(C2H4).Drawtheelectrondomaingeometryandthemoleculargeometryaroundthiscarbonatom,andindicatethehybridization.

6.A1.50LflaskcontainsamixtureofN2(g)andH2(g)atatotalpressureof1.25atm.ThemolefractionofN2is0.600.CalculatethepartialpressureofH2inthemixture.

7.Writethebalancedhalf-reactionsforthereductionandoxidationprocessesoccurringinthefollowingredoxreactionunderacidicconditions:

Mn(s)+PbO2(s)→MnO2(s)+Pb(s)

8.Describethetypesofintermolecularforcespresentinliquidethanol(C2H5OH).Whichoftheseforcesisprimarilyresponsibleforethanolsrelativelyhighboilingpointcomparedtodiethylether(C2H5OC2H5)?

9.Considertheacid-basereactionbetweenammonia(NH3)andwater(H2O):

NH3(aq)+H2O(l)?NH4+(aq)+OH-(aq)

TheequilibriumconstantforthisreactionisknownasK