钾离子电池技术文档Ultra-High Pyridinic N-Doped Porous Carbon Monolith Enabling High-Capacity K-Ion Battery Anodes for Both Half-Cell and Full-Cell Applications.pdfVIP

CommuniCation

CarbonMonolithswww.advmat.de

Ultra-HighPyridinicN-DopedPorousCarbonMonolith

EnablingHigh-CapacityK-IonBatteryAnodesforBoth

Half-CellandFull-CellApplications

YihaoXie,YuChen,*LeiLiu,PengTao,MoupingFan,NaXu,XiaoweiShen,

andChenglinYan*

obtainedintheresearchofLIBsmaybe

AnultrahighpyridinicN-content-dopedporouscarbonmonolithisreported,appliedtoKIBs.

andthecontentofpyridinicNreachesupto10.1%inoverallmaterialComparingKIBsandsodium-ionbat-

(53.4±0.9%outof18.9±0.4%Ncontent),beinghigherthanmostofteries(SIBs),akeyadvantageofKIBs

previouslyreportedN-dopingcarbonaceousmaterials,whichexhibitgreatlyisthelowerredoxpotentialoftheK/K+

redoxcouplethanNa/Na+(−2.94Vfor

improvedelectrochemicalperformanceforpotassiumstorage,especially++

K/Kcomparedwith−2.71VforNa/Na,

intermofthehighreversiblecapacity.Remarkably,thepyridinicN-dopedbothvsstandardhydrogenredox

porouscarbonmonolith(PNCM)electrodeexhibitshighinitialchargepotential).[12,13]Currently,t