第二周第3章：可逆过程与过程分析.pptx

2-4Reversibleprocess1.Workandprocesses

MotivationQuestionIfyoudriveacartoShanghai,whichwaydoyouuseinordertodobiggestworkandconsumetheleastenergy,fasterorslower?

Workofexpansionequalstotheproductoftheexternalforceanddistance:-δW=FdL=PeAdL=PedV?

Workisaprocessfunction.Workisdifferentfordifferentprocesseseventhoughtheyhavethesameinitialandfinalstates.a.??Theexpansiontovacuum(Freeexpansion)Pe=0δW=-PedV=0W1=0

b.TheexpansionatconstantexternalpressureδW=-PedVW2=-=-Pe(V2-V1)S