（6页PPT）晶体场理论B.pptVIP

B.EffectsofCrystal-fieldsplittingB1.spectrochemicalseries–NO2–enNH3H2OC2O42–OH–F–Cl–Br–I–strongestCFlargestDweakestCFsmallestD absorbs appearsweakest Ni(H2O)62+ R GB Ni(NH3)2+ O B Ni(en)32+ G VStrongestNi)42-– BV YellowROYGBVlowerEhigherEDE=hn~visibleregiond-dexcitation:en=ethylenediamineNi2+:t2g?egYellow

B.EffectsofCrystalfieldsplittingchargeonmetalgreatercharge?largerD(ligandsheldmoreclosely,thusinteractingmorestronglywithdorbitals,andexcertedastrongercrystalfield.)ROYGBVlowerEhigherE absorbs appearsFe(H2O)62+ R GFe