（40页PPT）几种典型的离子晶体结构.pptVIP

eg.FeFe2O4,FeMgFeO4magnetite(Fe3O4)=spinel(Fe3+(Fe3+,Fe2+)O4=B(AB)O4OanionsformfcclatticeFe3+(B)cationsin1/8tetrahedralholes,(Fe3+,Fe2+)(A)cationsinhalfofoctahedralholesSpinel[A]t[BB]oO4Anti-spinel[B]t[AB]oO4anti-spinelB[AB]O4---theMagneticpropertyDiamagnetismParamagnetismFerromagnetismH2O,Al2O3Fe(bcc),Co,NiAl,Cr,Cr2Cl3Anti-FerromagnetismMnOFerrimagnetismThehysteresisLoopBr residual inductionHc coercive fieldArea=hysteresislossPartiallyinversespinelZnFe2O4withhighsaturationmagnetizationAppl