MIT《计算机量子力学》教材 Lec19.pdfVIP

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  • 2026-09-17 发布于山东
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10.675LECTURE19

RICKRAJTER

1.Today

→ContinuumSolvation

→Onsager

→PCM

→Embedding,ONIOM

→QM/MM

2.Solvation

Lookingatthedi­chlorylethaneinthegasphase(transvsgauchepositions)

Inthegasphase,wetakethetransconfigurationas0energy,butthegauche

configurationas1kcal/mole.

Inasolvent,bothenergiesareessentiallythesameduetothesolventshigh

dielectricconstant.

WhatisΔEelec,solv(solvationen

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