储氢材料05-Hydrogen Storage materials.PPT

1) Zr1-xTixCr2 3.3 Zr-based multi-component alloys As x = 0~0.2, capacity H/M = 4.0~4.5 As x = 0.9~1.0, capacity H/M = ~3.3 2) Zr1-xTixMn2 As x = 0~0.6, capacity H/M = 3.6~4.0 As x = 0.6~1.0, capacity H/M = 0.3~3.6 3.3 Zr-based multi-component alloys 3) Zr(Cr1-xMx)2 (M=Fe, Co, Ni, ……) As x↑, → capacity H/M↓ 4) Zr(Cr1-xVx)2 As x↑, → capacity H/M↑ As x↑, → Peq↓, |?H| ↑ As x↑, pressure plateau → steeper 1) ZrNix (x=0~5) 3.4 Zr-based electrode alloys As x↓, charge capacity ↑, but dischargeability↓ Zr-based electrode alloys contains Ni element due to its electro-catalysis As x=1.2, the alloy has a highest discharge capacity Cmax= 210 mAh/g 3.4 Zr-based electrode alloys 2) Zr-V-Ni alloys (i) Zr(V1-xNix)2 (x=0.1~1.0) As x↑, charge capacity↓ As x=0.67, the alloy has only a single C15 type Laves phase and a highest discharge capacity Cmax= 298 mAh/g at 16 mA/g. (ii) Zr(V0.33Ni0.67)2+? ( ? = 0 ~ 1.0 ) As ? ↑, charge capacity↓ 3.4 Zr-based electrode alloys As ? =0.2~0.4, the alloy has a highest discharge capacity Cmax= 311 mAh/g. 3.4 Zr-based electrode alloys (iii) Zr(V0.25Ni0.75) ? ( ? = 1.0 ~ 4.0 ) The alloys have a main phase of C15 type Laves phase. As ?≤ 2.5, only a single C15 type Laves phase; As ? 2.0 (super-stoichiomertic), V → A side; As ? =2.0, discharge capacity Cmax= 394 mAh/g at 5 mA/g; As ? =3.0, discharge capacity Cmax= 800 mAh/g at 2 mA/g and Cmax= 400 mAh/g at 20 mA/g. 3) Zr-Cr-Ni alloys (i) Zr(Cr1-xNix)2 (x=0.15~0.65)－ZJU As x=0.35 (0.33~0.5), a highest discharge capacity Cmax= 305 mAh/g at 50 mA/g; 3.4 Zr-based electrode alloys As x=0.4~0.45, main phase structure changes from C15 to C14 3.4 Zr-based electrode alloys (ii) ZrCrxNi2-x (x=0.15~0.65)－J.M. Joubert As x1.0, a single C14 Laves phase; As x=0.8, a main phase of C15 and a secondary phase of C14; As x0.4, a main phase of C15 and a secondary phase of Zr7Ni10; the annealed alloys (1175℃×15 days) have only a single C15 Laves phase; as-c