电浆熔融焚化灰渣的著色处理及资源化研究.pdfVIP

第二屆資源工程研討會論文集 電漿熔融焚化灰渣的著色處理及資源化研究 1 2 3 4 5 黃明政 、鄭大偉 、曾錦清 、邱文通 、楊昇府 摘要 台灣地區預計每年將有 150~200萬噸之焚化灰渣產生。此等灰渣因含有重金屬及戴奧辛等有害物質，若未 加以妥善處理，勢必對生態環境造成嚴重之衝擊。本研究係採用電漿熔融處理技術，將焚化灰渣予以高溫熔融 處理，所得的安定化之玻璃質熔渣再經粉末燒結熱處理後製成微晶材料。在資源化製程中添加著色劑或脫色劑， 使微晶材料能具有不同的色澤，以利推廣應用於建材產業，有效解決國內有害廢棄物的堆貯環保問題。研究結 果顯示，添加二氧化鈦粉末製成的微晶材料，其結晶相為鈣鈦礦（ Perovskite ）、矽灰石（Wollastonite ）及鈣長 石（ Anorthite ）。其顏色為粉紅色且物理及機械性質均佳，為一個有潛力的再生材料。 關鍵詞： 焚化灰渣、電漿熔融、微晶材料、著色。 The reutilization of the coloration on incinerator ashes using thermal plasma technology M.Z. Huang 1 ，T. W. Cheng2 ，C. C. Tzeng3 ，W. T. Chiou4 ，S. F. Sheng5 ABSTRACT There are 30 municipal waste incinerators under construction in Taiwan that are expected to be complete at the end of 2005. It is estimated that these incinerators will produce over 1.5 to 2.0 million tones of incinerator ashes annually. Incinerator ashes contain large amount of hazardous materials such as heavy metals and dioxins. If these hazardous materials cannot be carefully treated, it will be endanger the ecological environment. This research work applied the thermal plasma technology to treat incinerator ashes. The vitrification slag can be produced the microstructure materials by sintering and heat treatment procedure. During the manufacture process, coloring agents or de-coloring agents may use in order to change the color of the microstructure materials to make high value of colorful building materials. The crystalline phases of the microstructure materials by adding TiO2 powder were perovskite, wollastonite and anorthite. The colored microstructure materials were pink and their physical/mechanical properties were great. Keywords: incinerator ashes, thermal plasma technology, microstructur