毕业设计（论文）--TiO3微波介质陶瓷的低温烧结工艺研究.docVIP

0.4CaTiO3-0.6(Li1/2Nd1/2)TiO3微波介质陶瓷 摘 要本文研究了烧结助剂BaCu(B2O5)（BCB）和烧结助剂2ZnO-B2O3玻璃（ZB）对0.4CaTiO3-0.6(Li1/2Nd1/2)TiO3（CLNT）介质陶瓷的烧结特性、相组成、微观形貌及介电性能的影响。通过LRC、XRD、SEM等实验设备检测CLNT陶瓷样片的介电性能、相组成、微观形貌，结果表明：添加少量的BCB能使CLNT陶瓷的烧结温度从1300oC降低至1050oC。随着BCB添加量的增加，介电常数下降，频率温度系数向负值偏移。添加4wt%BCB的CLNT陶瓷在1050oC烧结2h，获得了最佳的介电性能：εr=96.5，tanδ=0.017，τf=-13.6ppm/oC，满足高介多层片式微波元器件的设计要求。添加少量的ZB玻璃能使CLNT陶瓷的烧结温度从1300oC降低至950oC。随着ZB玻璃添加量的增加，介电常数先增大后减小，频率温度系数先趋于零后向负值偏移，介电损耗先下降后趋于稳定。添加3wt%ZB玻璃的CLNT陶瓷在950oC烧结2h，获得了最佳的介电性能：εr=91.13，tanδ=0.0133，τf=10.5ppm/oC，满足高介多层片式微波元器件的设计要求。MICROWAVE DIELECTRIC CERAMICS ABSTRACT The effects of BaCu(B2O5)(BCB) and 2ZnO-B2O3 glass(ZB) on sintering behavior, phase composition , microstructure and dielectric properties of 0.4CaTiO3-0.6(Li1/2- Nd1/2)TiO3(CLNT) microwave dielectric ceramics were investigated . It is detection phase composition, microstructure and dielectric properties of CLNT microwave dielectric ceramics by LRC, XRD and SEM instruments. It was found that a small amount of BCB additive lowered the sintering temperature of CLNT ceramics effective- ly from 1300oC to 1050oC. The dielectric constant (εr) decreased and the temperature coefficient of resonant frequency shifted to a negative value with the addition of BCB. CLNT ceramics with 4wt% BCB sintered at 1050oC for 2h showed the optimum dielectric properties: εr =96.5, tanδ= 0.017, and τf =-13.6ppm/oC,which satisfies the design demand of high dielectric constant and multilayer microwave components. The sintering temperature of CLNT ceramics was effectively lowered from 1300oC to 950oC by adding a small amount of ZB glass. With the addition of ZB glass, the dielectric constant (εr) increased first and then decreased and the temperature coefficient of resonant frequency shifted to zero and then to a negative value and the dielectric loss decreased and then to the stable. The CLNT ceramics with 3wt% ZB glass sintered at 950oC for 2h showed the optimum dielectric properties: εr =91.13, tanδ= 0.0133, and τf =10.5 p