ZnO_CdS纳米柱阵列太阳电池中光电转化效率的研究.docVIP

  ZnO/CdS 纳米柱阵列太阳电池中光电转化效 率的研究# 郭道友1，王金斌1，李培刚2，崔灿2，钟向丽1，王芳1，张克栋1，黄欢 5 10 15 20 25 30 35 40 娣2，金吉松2** （1. 湘潭大学材料与光电物理学院，湖南 湘潭 411105； 2. 浙江理工大学光电材料与器件中心，杭州 310018） 摘要：ZnO 纳米柱阵列具有迁移率高、比表面积大、易制备等优点被认为是理想的量子点敏化太阳电池光 阳极材料。采用简易的水热法在 FTO(F:SnO2)衬底上制备了 ZnO 纳米柱阵列，并通过连续离子层吸附反应 (SILAR)法在 ZnO 上原位沉积 CdS 量子点制备 ZnO/CdS 光阳极，研究了不同 SILAR 循环次数对电池光电 转化效率(IPCE)的影响。结果表明，CdS 拓宽了对可见光区的吸收，增强了对太阳光的利用率，同时，CdS 与 ZnO 构成型异质结增加了电子注入量子效率(ηinj)，IPCE 显著增加。10 次循环前，随着循环次数的增 加，ZnO/CdS 异质结界面增多，增加了电子和空穴的有效分离，并且 CdS 量子点增多，增强了对可见光的 光捕获效率，IPCE 逐渐上升；10 次循环后，随着循环次数的进一步增加，CdS 量子点层逐渐变厚，增加了 光生载流子被缺陷捕获的几率，ηinj 开始大幅减小，导致 IPCE 逐渐下降。 关键词：太阳电池；ZnO 纳米柱；CdS 量子点；光电转化效率；电子注入量子效率 中图分类号：TM914.4+2 A study on incident photon-to-current conversion efficiency of the ZnO/CdS nanorods arrays solar cell GUO Daoyou1, WANG Jinbin1, LI Peigang2, CUI Can2, ZHONG Xiangli1, WANG Fang1, ZHANG Kedong1, HUANG Huandi2, JIN Jisong2 (1. Faculty of Materials, Optoelectronics and Physics, Xiangtan University, Xiangtan, Hunan 411105; 2. Center for Optoelectronics Materials and Devices, Zhejiang Sci-tech University, Hangzhou, 310018) Abstract: Highly ordered, single-crystalline ZnO nanorod arrays (NRAs) would be the most desirable nanostructure in quantum dot-sensitized solar cells because of their efficient charge separation and transport properties. Vertically aligned ZnO NRAs have been fabricated by a facile hydrothermal method, and followed by in situ depositing CdS quantum dots (QDs) on ZnO by a successive ionic layer adsorption and reaction (SILAR) method. The effect of the number of SILAR cycles on the incident photon-to-current conversion efficiency (IPCE) was investigated. The experiments show that IPCE enhances sharply and broadens to the visible light area after the deposition of CdS QDs, leading to improve the utilization rate of the sun energy. Meanwhile, IPCE increases gradually with increasing SILAR sycles before 10 cycles, which is not only for increasing the light harvesting efficiency, but also for forming more II-type sem