二维Cd(II)配位聚合物的合成、晶体结构及荧光性质.docVIP

  二维 Cd(II)配位聚合物的合成、晶体结构及 荧光性质# 刘海燕1,2，马建方1** 5 10 15 20 25 30 35 40 （1. 多酸化学教育部重点实验室，东北师范大学化学学院，长春 130024； 2. 营口大学园化学工程系，辽宁 营口 115014） 摘要：以 Cd(CH3COO)2、5-羟基间苯二甲酸(H3L)和多齿含氮配体 2,4,6-三甲基-1,3-(二亚甲 基 苯 ) 二 (1,2,4- 三 氮 唑 ) (tbb) 为 原 料 ， 通 过 水 热 方 法 合 成 了 二 维 配 合 物 [Cd(HL)(tbb)(H2O)]·2H2O (1)。采用元素分析、红外光谱和 X-单晶衍射法表征了该配合物的 结构。结果表明：该化合物属于单斜晶系，空间群 P21/c，晶胞参数 a = 10.3374(5)，b = 29.3673(16)，c = 8.4323(5) ?，β= 104.206(5)o, V = 2481.6(2) ?3，Z = 4，F(000) = 1280，Dc = 1.683 g/cm3，R1 = 0.0405，wR2 = 0.0430 [ I 2 σ (I)]。配合物中 Cd(II)离子被 HL2-阴离子和 tbb 中性配体连接成一个二维的网状结构，相邻的网进一步通过氢键作用形成一个双层结构， 最终通过 π···π 的相互作用形成三维超分子结构。此外，还研究了该化合物在室温下的固体 荧光性质。 关键词：镉离子；配合物；晶体结构；荧光 中图分类号：O614 Synthesis, Crystal Structure and Luminescence of a Two-dimensional Cadmium (II) Coordination Polymer LIU Haiyan1,2, MA Jianfang1 (1. Keylab for polyoxometalate Science, Department of Chemistry,Northeast Normal University, ChangChun 130024; 2. Department of Chemical Engineering, Yingkou University Zone, LiaoNing YingKou 115014) Abstract: A novel 2D complex [Cd(HL)(tdb)(H2O)]·2H2O (1) was synthesized by the hydrothermal reaction of Cd(CH3COO)2, 5-OH-1,3-benzenedicarboxylate acid (H3L), and 1,3-bis(1,2,4-triazol-1-ylmethyl)-2,4,6-trimethyl benzene (tbb) ligand. The structure has been determined by single crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectrum. 1 belongs to monoclinic system, space group P21/c with a = 10.3374(5)，b = 29.3673(16)，c = 8.4323(5) ?，β= 104.206(5)o, V = 2481.6(2) ?3，Z = 4，F(000) = 1280，Dc = 1.683 g/cm3，R1 = 0.0405，wR2 = 0.0430 [ I 2 σ (I)]. In 1, the Cd(II) cations are linked by the HL2- anions and tbb ligands to form a two-dimensional (2D) sheet structure, and the adjacent sheets are further connected through the hydrogen bonds to exhibit double layer structures. Finally, the double layers are extended into a three-dimensional (3D) supramolecular structure through π-π interactions. In addition, the luminescent property of 1 is also discussed in the s