生物气通入固体氧化物燃料电池化学反应研究进展.docVIP

  生物气通入固体氧化物燃料电池化学反应 研究进展# 吴晓燕1，田禹1,3，周晓亮2，左微1，孔晓伟1** 5 10 15 20 25 30 35 40 （1. 哈尔滨工业大学市政环境工程学院，哈尔滨 150090； 2. 哈尔滨工业大学基础与交叉科学研究院理学中心，哈尔滨 150080； 3. 哈尔滨工业大学城市水资源与水环境国家重点实验室，哈尔滨 150090） 摘要：本文对以生物气为燃料的固体氧化物燃料电池化学反应进行了分析总结。在介绍生物 质可进行厌氧微生物分解产出主成分甲烷和二氧化碳、设备热解或气化释放氢气和一氧化碳 的生物气，以及固体氧化物燃料电池工作原理的基础上，总结两类生物气主成分、微量成分 硫化氢和氨气被分别资源化时的电极反应过程。最后，概括了电池利用生物气时碳沉积和硫 毒害化学过程，生物气在通入电池前和电池的阳极成分或结构改变来消除积碳和硫毒化的反 应行为。 关键词：生物气；固体氧化物燃料电池；化学反应；积碳；硫毒害 中图分类号：TK6 The research process of the chemical reactions of solid oxide fuel cell by biogas feeding WU Xiaoyan1, TIAN Yu1,3, ZHOU Xiaoliang2, ZUO Wei1, KONG Xiaowei1 (1. School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin, 150090, China; 2. Natural Science Research Center, Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin, Heilongjiang, 150080, PR China; 3. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, PR China) Abstract: The chemical reactions of the biogas-fueled Solid Oxide Fuel Cell(SOFC) have been summarized and analyzed in the paper. The main constituent of the biogas are methane and carbon dioxide, hydrogen and carbon monoxide, which could be volatilized by the anaerobic microorganisms degradation, pyrolysis or gasification of biomass respectively, and the electro-chemical mechanism of the SOFC are introduced. Based on the ingredient of the biogas and the SOFC mechanism, the electrical reactions of major and trace elements(H2S and NH3) in the biogas-fueled SOFC are compiled. At last, the chemical evolution of the biogas-fueled SOFC with carbon deposit and sulfur poisoning, and the chemical processes for eliminating them by pretreatment or the multivariate anode are listed in detail as well. Key words: Biogas; Solid Oxide Fuel Cell; Chemical reaction; Carbon deposit; Sulfur poisoning 0 引言 随着煤炭、石油等不可再生资源的日益减少，世界各国对可再生资源生物质的关注越来 越多。利用生物质能源的方式主要有直接燃烧、物化转化、生化转化和液化转化等[1-3]。而 固体氧化物燃料电池（SOFC）除利用氢气能获得高效的