13.Ⅲ－Ⅴ族半导体制备的新方法.ppt

4. Purity of Reagents and water 4.1 Unless otherwise indicated, it is intended that all reagents shall conform to （与…一致）the specification established by the Committee on Analytical Reagents of the American Chemical Society美国化学会分析试剂委员会, where such specifications are available.3 References to water shall be understood to mean（普通的） distilled water. INTERNAL INDICATOR METHOD 5. Reagents 5.1 Alkali Standard Solution (0.5 N)--Dissolve either 22g of sodium hydroxide (NaOH) or 33g of potassium hydroxide (KOH) (pellets or sticks球状或棒状) in water or in alcohol conforming to 5.2, and dilute to 1 L（litre） with the same solvent. Standardize to ±0.001 5.2 Ethyl Alcohol--Neutral methanol, neutral isopropanol异丙醇(91 to 99 %), neutral 95 % ethanol or neutral denatured alcohol（变性酒精, 工业酒精）conforming to Formula规则No. 30 or No. 3A of the U.S. Bureau of Internal revenue.（美国税务局） Note 1 --- In case of disagreement between purchaser and seller, aqueous alkali solution shall be used. 5.3 Phenolphthalein (酚酞) Indicator Solution--Dissolve 1 g of phenolphthalein in 100 mL of methanol. 5.4 Thymol百里酚 Blue Indicator Solution--Dissolve 0.1 g of thymol blue in 100 mL of methanol. 6 Procedure 6.1 Transfer 3.95 to 4.05 g of the sample（松香）, weighed to the nearest 0.001 g to a 250-mL Erlenmeyer flask（锥形瓶） and add 100mL of neutral alcohol. 6.2 Heat, if necessary, to dissolve the rosin, cool to room temperature (Note 2), and titrate the solution with the standard alkali solution using 1mL of either phenolphthalein or thymol blue indicator solution. With phenolphthalein, titrate to the first persistent稳定的 faint pink color（浅红色）, with thymol blue, titrate to a distinct（明显的） blue. NOTE 2--If the rosin does not remain in solution when it cools, use 200mL of alcohol instead of 100mL. 7. Calculation and Report 7.1 Calculate the acid number of the rosin, expressed as milligrams of KOH per gram of sample, as follows, and report to the nearest whole number. Acid number =(AN×56.1)/B