基于{VO3}nn-链连接两种有机配体的钒氧簇化合物.docVIP

  A composite based on {VO3}nn- chain containing two different types of organic ligands# WANG Xinfang, GUO Guiling, XU Yanqing, HU Changwen** 5 10 15 20 25 30 35 (Department of Chemistry, Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081) Abstract: The title compound, [Cu(1,10–phen)(en)H2O][Cu(en)2]0.5[V3O9] (1,10–phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}nn? chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10–phen)(en)H2O]2+ and [Cu(en)2]2+. The adjacent 1D {VO3}nn? chain are further bridged by [Cu(en)2]2+ complexes through Cu· · ·O weak interactions to form a 2D network. Key words: Polyoxometalates; Polyoxovanadates; Network; Cluster 0 Introduction Polyoxometalates (POMs) are a large family of anionic metal–oxygen clusters made up of early transition metals[1,2]. As one of most outstanding subclass in POM chemistry, polyoxovanadates (POVs) has generated significant interest owing to their intriguing structural diversity and potential applications in the fields of catalysis [3, 4] and lithium batteries [5, 6]. Up to now, a number of POV clusters containing the {VO3}nn? chain have been reported [7–10], such as, Cu(dien)V2O6·H2O[11], Cu(bipy)2V2O6[12], [M(dpa)V2O6] (M=Zn, Cu)[7] and [M(bipy)(H2O)(V2O6)] [13] synthesized under hydrothermal conditions and contain one type of organic ligand, however, no analogous compound containing mixed organic ligands have been reported. In this context, we simultaneously employ 1,10–phen and en to synthesize novel POMs with mixed organic ligands. Fortunately, we obtained a new compound, [Cu(1,10–phen)(en)H2O][Cu(en)2]0.5[V3O9] (1). 1 Experimental section 1.1 Materials and methods All reagents were purchased from commercial sources and used without further purification. C, H, and N elemental analyses were performed on a Perkin-Elmer 2