纳米TiO2光催化剂可见光化的最新进展.pdfVIP

纳米TiO2 光催化剂可见光化的最新进展/郭清泉等 ·11 · 纳米TiO2 光催化剂可见光化的最新进展* 郭清泉，王得泰，饶俊元 （广东工业大学轻工化工学院，广州 510006 ） 摘要 TiO2 是当前最具应用潜力的光催化剂之一,但仍然存在不足,主要表现在光吸收波长狭窄,吸收波长阈值在紫外区, 利用太阳光能量比例低等方面。对其进行改性,增加其光吸收波长范围,可以更充分地利用太阳光, 达到节约能源的目的。因 此，TiO2 可见光化一直是研究热点。综述了近几年国内外最新的纳米TiO2 可见光化改性的进展，如金属或非金属离子掺杂、 贵金属沉积、有机染料光敏化、溶剂热法制备等，并对 TiO2 光催化剂的应用前景进行了展望，认为溶剂热法简便易行，应 该重视和大力研究。 关键词 TiO2 可见光 溶剂热法 光催化剂 中图分类号：0614 The Latest Development of Visible-light Irradiation of Nano-sized TiO2 Photocatalyst GUO Qingquan ，WANG Detai ，RAO Junyuan （College of Light and Chemical Industry, Guangdong University of Technology ,Guangzhou 510006 ） Abstract TiO is a kind of photo-catalyst with the most applicable potentiality. But it also has some defects ，which mainly are 2 the range of the absorbable wavelengths being narrow , the absorbable wavelengths mostly belongjing to the ultraviolet region, hardly making use of sunlight as an energy source . It is modified to expand its absorbable wavelengths region to make full use of sunlight in order to save resource. So the research on visible-light Irradiation of nano-sized TiO2 photocatalyst is very hot. This paper summarizes the latest progress of improving visible-light photooxidation efficiency of nano-sized TiO2 in recent years, including metals or non-metal ion adulteration, deposition of noble metals ，the organic dyestuff photosensitization and solvothermal method ， etc. It also looks for the prospects of the nano-size TiO2 photocatalyst and puts forward that solvothermal method being simple and easy to operate should be paid attention to and researched extensiv