O3 氧化法处理晚期垃圾渗滤液有机污染物的特性.docVIP

第 44 卷第 2 期 2013 年 2 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.2 Feb. 2013  O3 氧化法处理晚期垃圾渗滤液有机污染物的特性 曾晓岚，丁文川，刘姣，李作鑫 (重庆大学三峡库区生态环境教育部重点实验室，重庆，400045) 摘要：采用气相色谱?质谱联合(GC-MS)技术，对 O3 氧化法处理前后晚期垃圾渗滤液中的有机污染物种类及去除 效率等进行分析，考察 O3 氧化法去除晚期渗滤液有机污染物的特性。研究结果表明：采用 O3 氧化 20 min 后， COD 去除率为 73.2%，BOD5 去除率为 38.7%，可生化性由 0.12 上升到 0.61，有机污染物种类由 66 减少到 48 种， 烯烃类、烷烃类及其他难降解有机物去除率为 50%以上，氧化出水羧酸类与醇类有机物量有所增加，在氧化过程 中有部分非酰胺类有机物转化成酰胺类有机物；采用 O3 氧化法处理晚期垃圾渗滤液，不仅能明显去除其中有机 污染物，而且能提高其可生化性，可以考虑作为晚期垃圾渗滤液的预处理技术。 关键词：O3 氧化法；晚期垃圾渗滤液；有机污染物；可生化性；预处理技术 中图分类号：X703.1 文献标志码：A 文章编号：1672?7207(2013)02?0843?04  Organic pollutant characteristics of aged landfill leachate with O3 oxidation ZENG Xiaolan, DING Wenchuan, LIU Jiao, LI Zuoxin (Key Laboratory of the Three Gorges Reservoir Region’s Eco-environments, Ministry of Education, Chongqing University, Chongqing 400045, China) Abstract: In order to explore organic pollutant characteristics of aged landfill leachate with O3 oxidation the types and removal rates of organic pollutants in leachate were analyzed by gas chromatograph-mass spectrometer (GC-MS) before and after O3 treatment. The results show that when the leachate is oxidized for 20 min, the removal rates of COD and BOD5 are 73.2% and 38.7%,respectively, the biodegradability increases from 0.12 to 0.61,the types of organic pollutants decrease from 66 to 48, the removal rates of alkenes, alkanes and other refractory organics are all above 50%,the amount of carboxylic acids and alcohols increases, and some non-amides transform into amides.O3 oxidation can be applied as one of the pretreatment processes of aged landfill leachate to remove the organic pollutants and improve the leachate biodegradability. Key words: O3 oxidation method? aged landfill leachate? organic pollutants? biodegradability? pretreatment process  城市生活垃圾渗滤液具有不同于一般城市污水的 特点，如成分复杂、水质水量变化巨大、有机物和氨 [1] 渗滤液中含有许多有毒物质，且质量浓度很高, 对