聚乙烯醇交联条件的研究.pdfVIP

聚乙烯醇交联条件的研究 摘要 聚乙烯醇(PVA)是一种很好的制备电纺丝基过滤材料的聚合物，为了使过滤材料具有良好的 性能，需要提高聚乙烯醇的耐水性和强度，因此我们对聚乙烯醇的交联性质做了研究。实验是选 用反丁烯二酸（fumaric acid）作为交联剂来制备聚乙烯醇-反丁烯二酸的交联膜，同时对交联 条件与交联膜的性能的关系做了研究。实验结果表明：聚乙烯醇能与反丁烯二酸在浓硫酸催化下， 高温脱水酯化交联而制得交联膜，并且交联度、交联时间和交联温度等交联条件的变化对交联膜 的性能有显著的影响。 通过实验我们发现交联度为 5%、交联时间为 2h、交联温度为 110℃时的交联膜的溶解度和耐 水性都比较好，并将其应用在静电纺丝中。 关键词：聚乙烯醇,反丁烯二酸,制备，交联,静电纺丝 1 聚乙烯醇交联条件的研究 Research on cross-linkage of PVA Zhen.Xinghao (School of Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617) ABSTRACT PVA is good alternative chemical for prepare electrospining base filtering material. In this case, the better water resistance and intensity are needed to make the filtering material good performance, thus, the cross-linkage parameter of PVA is discussed This work, we selected fumaric acid as cross-linkage chemical to prepare the fumaric acid /PVA cross-linkage film, meanwhile, we study the relationship between cross-linkage condition and membraning of the resulted PVA. The experimental result shows that the cross-linkage film can be framed in the present of oil of vitriol at high temperature and the performance of cross-linkage film can be greatly affected by the change of the condition, such as cross-linkage degree 、 cross-linkage time and cross-linkage temperature. In experiment, we find the crosslinked PVA film showed less solubility and good water resistance in the experimental conditions, cross-linkage degree 5% ,cross-linkage