核壳结构聚合物乳胶粒的制备与表征.pdfVIP

1 第25卷第2期 济南大学学报(自然科学版) Vo1．25 No．2 2011年4月 』Q Q UNIVERSITY OF JINAN(Sci Apr．2011 文章编号：1671—3559(2011)02—0123—05 核壳结构聚合物乳胶粒的制备与表征 张利娜，张立彬，朱晓丽，孔祥正 (济南大学 化学化工学院，Ih东 济南250022) 摘 要：选用苯乙烯和丙烯酸丁酯为聚合单体，改变乳化剂和引发剂用量，制备粒径分布较窄的苯丙乳液。以此为种子 胶乳，选用甲基丙烯酸甲酯(MMA)、丙烯酸乙酯(EA)和甲基丙烯酸(MAA)为第2步聚合单体，分别采用批量法和半连续滴 加法，制备出具有核壳结构且性能稳定的乳胶粒乳液。通过粒径分析和透射电镜，测试和比较分析两种乳胶粒粒径和形貌， 探讨MAA用量对核壳乳液的稳定性和乳胶粒粒径的影响。结果表明：当内核聚合物和外壳单体质量比为5：2，第2步壳单体 中MAA质量分数介于3％至5％时，半连续滴加法制备的乳胶粒粒径分布较窄，乳胶粒形貌规整，分布均匀，草莓型乳胶粒数 量较少，随着第2步聚合单体中MAA用量增多，乳液稳定性下降，乳胶粒粒径及分散指数增大。 关键词：核壳结构乳胶粒；乳胶粒形态；半连续乳液聚合 中图分类号：0631．5 文献标志码：A Preparation and Characterizati0n of Polymer Core／Shell Latex Particles ZHANG Li‘na，ZHANG Li-bin，ZHU Xiao·li，KONG Xiang-zheng (School of Chemistry and Chemical Engineering，University of Jinan，Jinan 250022，China) Abstract：Seed latex with narrow particle size distribution was first prepared by emulsion polymerization with styrene and butyl ac— rylate as monomers and varying amounts of emulsifiers and initiators，which was then used to achieve stable core／shelIIatex with second stage monomers consisting of methyl methacrylate，ethyl acrylate and methacrylic acid(MAA)，by batch and senli—continuous enmlsion polymerization．Particles size and morphology of the latexes prepared by the two processes were compared ． The effects of methacrylic acid amount on latex properties were studied．Experiment results show that monodisperse core—shell latex particles is obtained when the mass ratio of core／shell is kept at 5：2 with