环氧改性水性丙烯酸树脂的合成研究毕业论文.doc

环氧改性水性丙烯酸树脂的合成研究 摘 要：；；合成；应用Study on synthesis of waterborne acrylic resin modified by epoxy resin Abstract: With the development of science and technology, people tend to pay more emphasize on environment-protection and energy-saving. It is the consensus that the development directions for coatings are high solid content coatings, waterborne coatings and radiation-curable coatings. Waterborne UV-curable systems have many advantages, such as non-contamination, non-toxicity, non-skin irritation and safety of production. It becomes an attractive research all over the world. Waterborne Acrylate resin has some advantages, such as good glossiness,weather-resistant,chemical resistance, stabilization, non-contamination,nontoxicity, non-skin irritation, low price and safety of production, andbecome an green environ-mental product of low VOC. So it will be anattractive research and application areas. But it also has some disadvantages,such as high film forming temperature, low hardness,, poor anti一after tack,poor water-resistant, low adhesion, etc. So the high performance acrylatepolymer resin which can overcome those disadvantages will become research hotspot at present. On the experiment of EA modification, many factors such as different feed ways, reaction temperature, Initiator, EA content, etc, on thepolymerization and property of productwere discussed. The results showthat the copolymer of EA modify acrylate resin could be favorably preparedand the conversion rate of monomers is greater than 96%,when themultistep feeding is used, the reaction temperature is 82℃,the stirring rateis 150r/min}200r/min and the reaction time is 4h.Meanwhile,when thecontent of EA is 8% and NMA is 2%,the properities of copolymer is optimal,the hardness of film is 2H, the anti-after tack is level l,the adhesionstrength is level 2 and the water-resistant is 96h. In this paper, the water-souble Acrylate resin could besolution polymerization with Acrylate monomers, and makeprepared byprel