以流變性質之測量研究十六烷基三甲基澳化銨和聚丙烯酸之.pdfVIP

Bulletin of the College of Engineering, N.T.U. , No. 83, October 2001, pp. 13–20 國立臺灣大學 「台大工程」學刊 第八十三期 民國九十年十月 第 37–43 頁 37 國立臺灣大學 「台大工程」學刊 第八十三期 民國九十年十月 第 13–20 頁 Bulletin of the College of Engineering, N.T.U., No. 83, October 2001, pp. 37–43 以流變性質之測量研究十六烷基三甲基澳化銨和 聚丙烯酸之交互作用 RHEOLOGICAL STUDY OF INTERACTION IN THE POLY(ACRYLIC ACID)- CETYLTRIMETHYLAMMONIUM BROMIDE SYSTEM 林芳才* 陳興鉑** 陳炳宏† Perry F. C. Lim Shing Bor Chen Bing -Hung Chen * ** † B.S. Assistant Professor Assistant Professor (corresponding author) Department of Chemical and Environmental Engineering, National University of Singapore 10 Kent Ridge Crescent, Singapore 119260 Abstract Interactions between anionic polymer, poly(acrylic acid) (PAA) and cationic surfactant, cetyltrimethylammonium bromide (CTAB) are investigated by light scattering and rheological measurements. Upon addition of 2 wt% CTAB to PAA solutions with polymer concentration ranging from 0.04 to 0.1 wt%, evidence of transition from shear-thinning to nearly Newtonian behavior is observed. The origin of this observation appears to be lying in the fact of formation of more compact PAA/CTAB aggregates. It is confirmed by the measurements of static light scatteri