A_b复合成核剂对等规聚丙烯结晶形态结构和力学性能的影响.docVIP

  a/b 复合成核剂对等规聚丙烯结晶形态结构 和力学性能的影响# 薛利廷1,2，王广龙1,2，张晓黎1,2，陈静波1,2** 5 10 （1. 郑州大学材料科学与工程学院，郑州 450001； 2. 国家橡塑模具工程研究中心，郑州 450002） 摘要：本文使用不同含量的α成核剂（DMDBS）和β成核剂（WBG-）复合改性等规聚 丙烯（iPP），重点研究了其对 iPP 结晶形态结构和力学性能的影响。用差示扫描量热法（DSC） 分析了改性 iPP 的熔融行为，并计算了α晶和β晶的结晶含量。利用偏光显微镜（PLM）观 察了改性 iPP 晶体尺寸及其结晶行为。实验表明：复合成核剂的加入可以细化晶粒，β晶的 熔融温度随着β成核剂含量的增加而升高。注塑试样的拉伸实验和缺口冲击实验结果表明， 0.1%的 DMDBS 与 0.2%的 WBG-II 进行复合时样品的拉伸强度和冲击强度同时得到提高。 关键词：等规聚丙烯；复合成核剂；晶体形态；力学性能 中图分类号：TB324 15 Effect of a/b Compouned Nucleating Agents on Structure and Properties of Isotactic Polypropylen XUE Liting1,2, WANG Guanglong1,2, ZHANG Xiaoli1,2, CHEN Jingbo1,2 (1. School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001; 20 25 30 35 2. National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou 450002) Abstract: Crystallization and mechanical properties of iPP modified by compounding nucleating agents (NAs) with different contents of α nucleating agent, di(3,4-dimethyl)dibenzaldehyde sorbitol (DMDBS), and β nucleating agent, rare earth (WBG-II) were studied in this paper. The melting behavior of modified iPP was analyzed by DSC, measured enthalpy was used to be calculated α and β relative crystallinity. The spherulite sizes and crystallization behavior were detected by polarized optical microscopy (PLM).The results demonstrated that the adding of α/β compounded nucleating agents could significantly decrease the crystal size. The melting temperature of β form crystal was changed with the increase of β nucleating agent. Tensile and impact strengths of injection molded specimens were tested, tensile and impact strengths of samples with 0.1% DMDBS and 0.2% WBG-II could be simultaneously improved. Key words: isotactic polypropylene; compounded nucleating agents; crystal morphology; mechanical property 0 引言 聚丙烯（PP）具有较小的相对密度、良好的耐溶剂腐蚀性、无毒、绝缘、易加工成型 等优点。但是 PP 的成型加工周期长，制品尺寸稳定性和冲击韧性较差，制品的光泽度和透 [1,2] 剂改性聚丙烯可提高聚丙烯的刚性和光学性能，而 β 成核剂改性聚丙烯则能提高聚丙烯的冲 40 击强度。因此，α/β 复合成核剂改性聚丙烯吸引了众多研究者的关注，Z