AlCr23复合粉体的制备及红外反射特性研究.pdfVIP

第 28 卷 第 5 期 无 机 材 料 学 报 Vol. 28 No. 5 2013 年 5 月 Journal of Inorganic Materials May, 2013 文章编号: 1000-324X201305-0545-06 DOI: 10.3724/SP.J.1077.2013.12395 Al/Cr O 复合粉体的制备及红外反射特性研究 2 3 袁 乐, 翁小龙, 卢 虎, 邓龙江 电子科技大学 电子薄膜与集成器件国家重点实验室, 微电子与固体电子学院, 成都 610054 摘 要: 采用液相 沉淀法, 制备 了在片 状铝粉 表面包 覆 Cr O 的复合 粉体颜 料, 利用 XRD 、SEM 、UV/VIS/NIR 分光 2 3 光 度计、FTIR 红 外光谱 仪等方 法对颜 料相结 构、形貌、光 谱及红 外反射 特性等 进行了 测试表 征。结 果表明, Cr O 2 3 3+ 包 覆层对 光谱反 射特性 的影响 随波长 变化而 异, 波 长越短, 包覆 前后反 射率的 变化越 大。 当 Cr :Al 摩尔 比为 0.2:1.0 时, Al/Cr O 复合 颜料在 可见光 波段的 反射率 下降接近 50%, 颜 色明度 参数 L*降低 15, 而 8~14 μm 波段 红外反 射率 2 3 下降不 到 10% 。分析表明, 包覆层对不同波长辐射的吸收系数以及表面粗糙度的差异导致了上述结果。该复合颜 料对于低明度和光泽度的低红外发射率涂层设计有重要研究价值。 关 键 词: 片状铝粉; Cr O ; 发射率; 明度; 包覆 2 3 中图分类号: TQ637 文献标识码: A Preparation and Infrared Reflection Performance of Al/Cr O Composite Particles 2 3 YUAN Le, WENG Xiao-Long, LU Hu, DENG Long-Jiang State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China Abstract: The composite pigments were prepared by co-precipitation coated Cr O on the surface of flake alumi- 2 3 num powders. Phase structure, surface morphology and reflectance spectra of the composite pigment were charac- terized by XRD, FE-SEM, UV/VIS/NIR spectroscopy and Fourier transform infrared spectrometer. The result shows that the influence of cover treatment with Cr O on the reflectance spectra at various radiation wavelengths is 2 3 3+ different. The shorter the wavelength is, the stronger the influence is. When the molar ratio of Cr to Al is 0.2:1.0, compared with the uncoated flake aluminum powders, its average reflectance of visible spectrum and brightness L* drop to 50% and 15, respectively. However, the infrared emissivity of 8?14 μm waveband increases less than 10%It mainly ascribes to the difference of surface roughness and absorption coefficient for different radiation wave- lengths. Thus, the composite particles play a vital role in designing the low infr