三种添加剂对纳米晶锌镀层电沉积行为及结构的影响.pdfVIP

2010 年第68 卷 化 学 学 报 Vol. 68, 2010 第6 期, 531～534 ACTA CHIMICA SINICA No. 6, 531～534 ·研究论文· 三种添加剂对纳米晶锌镀层电沉积行为及结构的影响 伍玉琴 李谋成* 辛森森 胡方坚 沈嘉年 (上海大学材料研究所 上海 200072) 摘要 运用极化曲线、XRD 和SEM 研究了三种有机添加剂对酸性硫酸盐溶液中锌电沉积行为以及纳米晶锌镀层结构 的影响. 结果表明, 十六烷基三甲基溴化铵(CTAB)、4-苯基-3-丁烯-2-酮(BA)和聚乙二醇(PEG)三种添加剂之间具有较 强的协同作用, 采用三者组成的混合添加剂可制备出光亮致密的纳米晶锌镀层. 镀层晶粒细化的主要原因在于混合添 加剂可有效提高锌的沉积过电位, 使锌沉积过程中的晶核形成速率增大. 关键词 锌; 电沉积; 纳米晶; 有机添加剂 Effect of Three Additives on Electrodeposition Behavior and Structure of Nanocrystalline Zinc Coatings Wu, Yuqin Li, Moucheng* Xin, Sensen Hu, Fangjian Shen, Jianian (Institute of Materials, Shanghai University, Shanghai 200072) Abstract The influence of three organic additives on the direct current electrodeposition behavior of zinc from acidic sulfate baths and the structure of nanocrystalline zinc coating were investigated by potentiody- namic polarization techniques, X-ray diffraction and scanning electron microscopy. The results show that there is intensive synergistic effect among cetyltrimethylammonium bromide (CTAB), benzalacetone (BA) and polyethylene glycol (PEG). A bright and compact nanocrystalline zinc was produced due to the coexis- tence of such three additives. The combination of these additives can increase the overpotential and nuclea- tion rate of zinc electrodeposition markedly, which gives rise to the grain refinement of zinc deposits. Keywords zinc; electrodeposition; nanocrystalline; organic additive 造成汽车损坏的重要原因之一是腐蚀, 汽车腐蚀不 多优点, 如易于实验室向工业现场转变, 适合用于制备 仅造成巨大材料、能源的浪费, 而且带来环境的污染和 纳米晶金属、合