微螺旋炭纤维的制备与表征.pdfVIP

第 27 卷 第 5 期 无 机 材 料 学 报 Vol. 27 No. 5 2012 年 5 月 Journal of Inorganic Materials May, 2012 文章编号: 1000-324X(2012)05-0541-04 DOI: 10.3724/SP.J.1077.2012.00541 微螺旋炭纤维的制备与表征 李 宁, 寇开昌, 晁 敏, 张冬娜, 吴广磊, 马利鹏 (西北工业大学 理学院 应用化学系, 西安 710129) 摘 要: 采用溶剂热法合成出硫化镍, 并将其作为催化剂, 催化热解乙炔制备出微螺旋炭纤维. 通过 SEM、FT-IR 和 XRD 分析了催化剂和微螺旋炭纤维的形貌和微观结构. 结果表明: 硫化镍催化颗粒表面光滑、为规则的六方相结 构, 直径为 1~2 μm; 微螺旋炭纤维具有双螺旋结构, 截面为矩形, 具有相同的螺径. 微螺旋炭纤维分子结构中既含 有不饱和的 C=C 双键, 又含有饱和的−CH2−和−CH3 基团, 其微观结构整体有序度较差, 存在一定量的无定型炭和 晶体缺陷, 石墨化度低. 关 键 词: 微螺旋炭纤维; 溶剂热; 硫化镍; 微观结构; 催化热解 中图分类号: TQ342 文献标识码: A Preparation and Characterization of Micro-coiled Carbon Fibers LI Ning, KOU Kai-Chang, CHAO Min, ZHANG Dong-Na, WU Guang-Lei, MA Li-Peng (Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xian 710129, China) Abstract: Carbon microcoils (CMCs) were synthesized by the catalytic decomposition of acetylene using nickel sulfide particles as the catalyst which prepared by solvothermal method. The morphology and microstructure of the catalyst and micro-coiled carbon fibers were examined by SEM, FT-IR and XRD. The results showed that the catalyst was regular hexagonal phase nickel sulfide with its diameter of 1−2 μm and a smooth surface. CMCs have double helix structure, rectangular cross-section and identical coil diameter. The molecular structure of CMCs contained both unsaturated –C=C– and saturated –CH – and –CH groups. The