费托合成中的水煤气变换反应.pdfVIP

化学通报 2006 年 第69 卷 w076 费-托合成中的水煤气变换反应 * 蔡丽萍 沈菊李 唐浩东 刘化章 杨霞珍 (浙江工业大学工业催化研究所 杭州 310014) 摘 要 评述了近年来有关费-托合成中的水煤气变换反应的研究进展，着重介绍了费-托反应条件下 发生的水煤气变换反应的热力学分析、反应机理和动力学。同时介绍了催化剂制备、操作参数等因素对水 煤气变换反应的影响。 关键词 水煤气变换反应 费-托合成 机理 动力学 The Water Gas Shift Reaction in Fischer-Tropsch Synthesis * Cai Liping, Shen Juli, Tang Haodong, Liu Huazhang , Yang Xiazhen (Catalysis Institute of Zhejiang University of Technology, Hangzhou 310014) Abstract In this paper, the development of research on the water gas shift(WGS) reaction in the Fischer-Tropsch synthesis (FTS) was reviewed. The WGS reaction is important when synthesis gas with nonstoichiometric amounts of hydrogen is used, whereas CO efficiency is decreased accordingly. Its thermodynamic analysis, reaction mechanism and kinetics in conjunction with the FTS are presented. The WGS reaction is equilibrium or close to equilibrium reaction under Fischer-Tropsch conditions on catalysts with a high water gas shift activity such as iron-based FTS catalysts, which may operate via a mechanism with a formate species or via a direct oxidation mechanism. The kinetic studies assumed that the WGS reaction proceeds on a different catalytic site than the FTS. The effects of catalyst preparation and operation parameters on the WGS reaction activity are also summarized. The importance and prospect of research on the WGS reaction under the Fischer-Tropsch conditions are proposed. Key words Water gas shift reaction(W