封端型水性聚氨酯合成及应用研究.pdfVIP

第27 卷第5 期 印染助剂 Vol．27 No．5 2010 年5 月 TEXTILE AUXILIARIES May 2010 封端型水性聚氨酯的合成及应用研究 卢啸旸，王 炜 （东华大学化学化工与生物工程学院，生态纺织教育部实验室，上海 201620） 摘 要：以异佛尔酮二异氰酸酯(IPDI)、聚醚多元醇、二羟甲基丙酸(DMPA)为主要原料,采用NaHSO3 封端,合成了一系列脂肪 族水性聚氨酯乳液,探讨了影响水性聚氨酯预聚反应、中和反应、封端反应的各个因素,优化了水性聚氨酯的合成工艺,得到了综合性 能较好的封端型水性聚氨酯(WPU).产品用于棉抗皱整理,可提高织物回复角, 同时提高织物强力. 关键词：水性聚氨酯; 封端; 合成; 性能 + 中图分类号: TQ610.4 8 文献标识码: A 文章编号: 1004－0439(2010)05－0026－04 Study on synthesis and application of blocked waterborne polyurethane LU Xiao-yang, WANG Wei (Key Laboratory of Science Technology of Eco-textile, Ministry of Education, College of Chemisty, Chemical Engineering Biotechnology, Donghua University, Shanghai 201620, China) Abstract ： A series of blocked aliphatic waterborne polyurethane emulsions were prepared with isophorone- diisocyanate (IPDI), polyether polyols, dimethylolpropionic acid (DMPA) as materials and NaHSO3 as blocking age- nt. The influencing factors of the pre-polymerization reaction, neutralization reaction and blocking reaction were investigated and the synthetic process conditions were optimized. Then the blocked aliphatic waterborne polyurethane (WPU) with better comprehensive properties were obtained. The WPU was used to anti-crease fini- shing of cotton fabric. The results showed that the wrinkle recovery angle of the treated fabric were increased and the strength retention were also enhanced. Key words ： waterborne polyurethane; terminal blocking; synthesis; properties 水性聚氨酯具有安全不燃烧、无公害等优点,并保