温度对植酸转化膜的影响.docVIP

转化时间对AZ31B镁合金植酸转化膜的影响研究 高焕方1，1，谭怀琴1，黄国文1，孙强2，陈汉林3 （1 重庆理工大学化学化工学院，重庆 400050；2驻791厂军事代表室，重庆 4013362；3 驻296厂军事代表室，重庆 400050） 摘 要: 为了探讨转化时间对镁合金植酸转化膜防腐性能的影响，应用析氢实验、Tafel分析方法及SEM对AZ31B镁合金在植酸溶液中不同时间所形成转化膜的防腐性能及表面微观结构进行了研究。结果表明转化时间对镁合金植酸转化膜的防腐性能有较大的影响，当转化时间较短时，转化膜的防腐性能随着转化时间的增加而增加，并在转化时间为40min时，其转化膜防腐性能最佳，此后随着转化时间的进一步增加，转化膜的防腐性能随之下降。植酸转化膜Mg, Al, Zn, O, P元素 转化膜存在一定的裂纹，且裂纹处仍有很薄的一层植酸转化膜。此外，析氢实验、Tafel实验及动力学分析表明植酸转化试样相比于未处理试样，具有更好的防腐性能。 关键词: 植酸；转化时间；镁合金；转化膜；防腐 中图法分类号：TG174.4 文献标识码： A Influence of Conversion Time on Phytic Acid Conversion Coating on AZ31B Magnesium Alloy Gao Huanfang1*, 1, Tan Huaiqin1, Huang Guowen1,Sun Qiang 2,Chen Hanlin3 （1.College of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400050, China；2. Military Representative Office at Factory No.791, Chongqing 400050, China；3. Military Representative Office at Factory No.296, Chongqing 400050, China） Abstract: The phytic acid conversion samples were formed on AZ31B magnesium alloy at different time. The anticorrosive performance, morphology, composition and functional groups of the conversion samples were studied by hydrogen evolution method, Tafel, SEM and EDS, respectively. The results indicate that the conversion time has obviously influence on the properties of the phytic acid conversion coating. The anticorrosive performance of the samples is increased with the increase of conversion time when the conversion time is short. When the conversion temperature is 40 min the conversion sample has best anticorrosive performance. After this, the anticorrosive performance of the samples is reduced with the increase of conversion time. The main elements of the coating are Mg, Al, Zn, O and P. The conversion coating also has few cracks, and the thin coating is formed on the crack. Furthermore, hydrogen evolution method, Tafel and the kinetics analysis shows the phytic acid conversion sample has better corrosion resistance than untreated sample. Keywords: phytic acid;