接枝法制备温度响应型PVDF-g-PNIPAM复合膜研究.pdfVIP

现代食品科技 Modern Food Science and Technology 2013, Vol.29, No.1 接枝法制备温度响应型 PVDF-g-PNIPAM 复合膜的研究 肖凯军，詹婷，陈仁菊 （华南理工大学轻工与食品学院，广东广州 510642） 摘要：开展碱改性-接枝法制备温度响应型聚偏氟乙烯（PVDF ）复合膜的制备工艺的研究。通过强碱改性法，将PNIPAM 单体 接枝到 PVDF 基膜上，制备出具有温度响应特性的智能膜。通过测定低临界溶解温度（LCST ）、纯水通量、截留率等指标，研究不 同的交联剂浓度、交联反应温度、接枝率对智能膜的温度响应性能的影响，并采用傅氏变换红外光谱对复合膜的化学成分进行了表征。 红外光谱分析证实已经接枝上了温敏基团PNIPAM ，实验结果表明，制备此温度响应型聚偏氟乙烯复合膜的最佳工艺条件为：交联剂 （MBAA ）浓度0.02 mol/L，接枝率7%，交联反应温度50 ℃~60 ℃。结果同时表明复合膜具有良好的温度响应性能及抗污染性。 关键词：温度响应；聚偏氟乙烯复合膜；接枝法；强碱改性 n 文章篇号：1673-9078(2013)1-81-87 c . Thermo-sensitive PVDF-g-PNIPAM Membrane d Preparation via Grafting Copolymerization Method o XIAO Kai-jun, ZHAN Ting, CHEN Ren-ju o (College of Light Industry and Food Sciences, South China University of Technology, Guangzhou 510640, China) f Abstract: Carry out the research of preparation process of temperature-responding polyvinylidene fluoride(PVDF) composite intelligent n membrane by grafting copolymerization method . PNIPAM monomer is grafted onto the PVDF-based membrane by alkali modification method r in order to prepare composite intelligent film that having temperature response characteristic. With the determination of the lower critical e temperature (LCST), pure water flux, retention and other indicators, it figure out that how the different cross-linking concentration, the tem