毕业论文--ZrCuAlNb大块非晶合金的耐蚀性研究.doc

摘 要 近年来，块状非晶合金的研究取得了重大进展，人们开发出了许多块状非晶合金系列。非晶合金在化学结构方面由单一的均匀固体相组成，没有像晶体那样的结构缺陷，如位错、晶格缺陷、晶界、孪晶、层错等。非晶态合金中原子排列是长程无序的，所以非晶合金的这种化学结构的均一性，使得非晶态合金具有良好的耐腐蚀性能。深入研究块状非晶合金的抗腐蚀性能无论在理论上还是实际中都具有十分重要的意义。 本文利用 X-Ray 衍射仪、电化学工作站、电弧炉等设备手段、制备研究、分析了ZrCuAlNb大块非晶的耐蚀性，利用浸泡法和电化学法研究了ZrCuAlNb大块非晶合金在酸碱盐中的腐蚀行为。 实验结果表明：利用浸泡实验和极化曲线分析可知，ZrCuAlNb块体非晶合金在HNO3、H2SO4、NaOH溶液中有较好的耐蚀性，同时还得出在氢氧化钠溶液中Nb1、Nb2的耐蚀性更好一些，而Nb含量的多少对非晶合金在硫酸和硝酸中耐蚀性的影响不是太明显。非晶合金在含Cl-的环境中耐腐蚀性较差，并且随着Nb含量的增加耐蚀性逐渐增强，尤其是在盐酸溶液中其耐蚀性是最差的，通过比较发现Nb5在含有Cl-溶液中耐蚀性是最好的。 关键词：非晶合金 腐蚀性 失重法 极化曲线 溶液 Abstract Recently，the studies on bulk amorphous alloys have achieved a great development．Amorphous alloy in chemical structure of solid phase by a single component, not even as crystal structure of such defects such as dislocations, lattice defects, grain, crystal, dislocations non-infarct-related etc. Amorphous alloys in disorder, is long-range arrangement of amorphous alloy so the chemical structure, the uniformity of amorphous alloys has good corrosion resistance It is very important to further study the corrosion behavior of bulk amorphous alloys in theory and application． The corrosion resistance of ZrCuAlNb bulk amorphous alloy have been investigated by electrochemistry workstation, X-Ray diffraction and other instruments.And used soaking method and electrochemical method studied the corrosion behavior of ZrCuAlNb block amorphous alloy in acid,alkali and salt solution. The result of immersion test and polarization curve analysis shows that ZrCuAlNb block amorphous alloy has a good corrosion resistance in HNO3,H2SO4 and NaOH solution and also obtained in the NaOH solution Nb1, Nb2 better corrosion resistance. The number of Nb content on the corrosion resistance of amorphous alloys is not too obvious in H2SO4 and HNO3 solution. Amorphous alloy in chloride ion environments poor corrosion resistance and with the increase of Nb content gradually increased corrosion resistance,especially in the hydrochloric a