河南省西峡县石门沟钼矿床流体包裹体特征和成矿时代研究.pdfVIP

1000-0569／2011／027(05)一1439．52 ActaPetrologicaSinica 岩石学报 河南省西峡县石 门沟钼矿床流体包裹体特征和 成矿时代研究 邓小华 姚军明 李晶 刘国飞 DENGXia0Hua．YA0JunMing ．LIJing。andLIUGuoFei 1．北京大学造山带与地壳演化重点实验室，北京 100871 2．中国科学院广州地球化学研究所 矿物学与成矿学重点实验室，广州 510640 3．紫金矿业集团股份有限公司，上杭 364200 4．河南省地质矿产勘查开发局第一地质勘查院，郑州 450000 1．LaboratoryofOrogenandCrustEvolution，PekingUniversity，Being100871，China 2．KeyLaboratoryofMineralogyandMetaUogeny，GuangzhouInstituteofGeochemistry，ChineseAcademyofSciences，Guangzhou510640，China 3．ZqinMiningGroup，Shanghang346200，China 4．No．1GeologicalExplorationInstituteofHenanProvince，Zhengzhou450000，China 2010．11～13收稿．2011-03．25改回 ． DengXH ，YaoJM ，LiJandLiuGF．2011．FluidinclusionandRe-Osisotopicconstraintsonthetimingandoriginofthe ShimengouModeposit。XixiaCounty，HenanProvince．ActaPetrologicaSinica。27(5)：1439—1452 Abstract The Shimengou deposit，containsporphyry and quartzvein—type molybdenum mineralization，ismainly hosted in granitoidsoccursintheErlangpingTerrane，northernEastQinlingOrogen．Thequartzvein—typemineralizationcanbedividedinto early，middle and latestages，characterized by assemblages ofquartz—pyrite，quartz·molybdenite—polymetallic sulfide and quartz— carbonate，respectively．The samplesfrom porphyry mineralizationcontainthreedifferenttypesoffluidinclusions，includingCO2一 H2O，NaC1一H20 anddaughtermineral—bearinginclusions．Theprimary fluidinclusionsinqua~zformedinearlystageofquartzvein— typemineralizationaremajorofthree—phaseCO2一H2Oandtwo—phaseNaC1一H2O，whilethoseinmiddleandlatestagesmineralsonlyof NaC1一H2Oinclusions．ThequartzofpoprhyrymineralizationtrappedtheinitialhighsalinityH2O—CO2一NaC1orefluidsattemperatureof 270～400％ with thepressureupto155MPa．correspondingtodepthof 5．4kni．From earlytolate stagesofquartzvein—type mineralization，homogeneoustemperaturesoffluidinclusionsdecreaserfom240～330％ (E)，through170—290jC (M)，to150— 200％ (L)；salinitieschangefrom2％～10％NaCleqv(E)，through2％ ～8％NaCleqv(M)，to1％～6％NaCleqv(L)．Therange oftemperaturesandsa