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Trans. Nonferrous Met. Soc. China 23(2013) 3808−3815
Thermodynamics and kinetics of carbothermal reduction of
zinc ferrite by microwave heating
1,2,3 4 1,2,3 1,2,3 1,2,3
Xin WANG , Da-jin YANG , Shao-hua JU , Jin-hui PENG , Xin-hui DUAN
1. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology,
Kunming 650093, China;
2. Key Laboratory of Unconventional Metallurgy, Ministry of Education,
Kunming University of Science and Technology, Kunming 650093, China;
3. Engineering Laboratory of Microwave Application and Equipment Technology, Kunming 650093, China;
4. Kunming Metallurgy Research Institute, Kunming 650093, China
Received 21 September 2012; accepted 11 October 2013
Abstract: The kinetics of carbon reduction of ZnFe O in the temperature range of 550−950 °C was investigated in a microwave
2 4
tank-type reactor. The mechanism of formation of ZnO and Fe O /FeO by the decomposition of ZnFe O was detailed using the
3 4 2 4
equilibrium calculations and thermodynamics analysis by HSC chemistry software 6.0. In addition, the effects of decomposition
temperature, the C/ZnFe O ratio, the particle size and the microwave power were assessed on the kinetics of decomposition. Zn
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