采取变压吸附技术回收氯乙烯精馏尾气.pdfVIP

第 期 中国氯碱 12 No．12 年 月 39 2009 12 China Chlor－Alkali Dec.,2009 采用变压吸附技术回收氯乙烯精馏尾气 刘包生 （宁夏西部聚氯乙烯有限公司，宁夏 石嘴山 753202 ） 摘 要：介绍了变压吸附回收氯乙烯精馏尾气新工艺，并与活性炭吸附回收工艺进行了比较，实际运 行效果表明该工艺运行稳定、操作简便，具有PLC 系统自动控制、安全性能好等特点。 氯乙烯、 乙炔回 收率均达到99.9％ ，排放尾气中氯乙烯质量浓度小于36 mg／ m3 ，乙炔质量浓度不大于150 mg／ m3 ，消耗 大幅降低，在任何负荷下，装置都能稳定运行，经济和社会效益显著。 关键词：氯乙烯尾气；变压吸附；回收 中图分类号： 文献标识码： 文章编号： TQ325.3 B 1009－1785(2009)12－0039-04 Tail gas decontamination of vinyl chloride by pressure swing technology and recovery of vinyl chloride and acetylene LIU Bao-sheng (Ningxia West PVC Co., Ltd., Shizuishan 753202, China) Abstract: The new process of rectification tail gas of vinyl chloride by pressure swing technology was introduced. The pressure swing technology and activated char absorption process were compared, and the former was stable and simple operation, and PLC control system was automatic. The recovery rate of vinyl chloride and acetylene was 99.9 %. Vinly chloride content in tail gas was less than 36 mg/m3, and acetylene content was less than 150 mg/ m3. Consumption was significantly reduced. The equipment was still stable operation in any load. And the economic profits and social benefit was obvious. Key words: tail gas of vinyl chloride; pressure swing; recovery 宁夏西部聚氯乙烯有限公司始建于2003 年，采 质为 16 MnR 的盘管式吸附器，即活性炭吸附工艺。 用离子膜法烧碱技术，于 年正式投产。 设计生 工艺流程图见图 。 2005 1 产能力为 万 ，