采取电动修复增强技术去除电镀污泥中重金属.pdfVIP

中国环境科学 2010，30(3)：349-356 China EnvironmentalScience 采用电动修复增强技术去除电镀污泥中重金属 彭桂群，田光明 (浙江大学环境工程系，浙江 杭州 310029) 摘要：为提高电动修复技术去除电镀污泥中的重金属(Cu，Pb，Zn，Cr,Ni)的效率，采用污泥预酸化处理及阴极 pH值控制处理2种途径进行 强化，反应过程中电压为 32 处理时间为 7d’结果表明，电镀污泥酸化 pH 值至 4．5时，污泥中重金属的可移动性明显提高了，依次为 CrNiZnCuPb；污泥预酸化加阴极pH值控制处理能使电镀污泥中zn、Ni、Cu和Pb交换态、碳酸盐结合态和有机硫化物态转化为可 溶离子态，转化量大小依次为NiZnCuPb，且该处理Zn、Ni、Cu和 Pb的去除率分别达到74．02％、68．38％、39．22％、21_37％；但污泥预 酸化及阴极 pH值控制处理都不利于 cr的去除，对照处理cr去除率为77．83％，污泥预酸化处理去除率降为40．65％，污泥预酸化加阴极pH 值控制处理降至 12．80％． 关键词：电镀污泥：电动修复；重金属：形态；连续提取 中图分类号：X705 文献标识码：A 文章编号：1000—6923(2010)03—034908 Removalofheavy metalsfrom electroplating sludgebyeleetrokineticenhancementtechnology．PENG Gui—qun， TIANGuangm·ing’(DepartmentofEnvironmentalEngineering，ZhejiangUniversity,Hangzhou310029，China)．China EnvironmentalScience，2010，30(3)：349-356 Abstract：Toenhancetheheavymetals(Cu，Pb，Zn，CrandNi)removalfromelectroplatingsludgebyelectrokinetic(EK) ehnancementtechnology,theEKexperimentswerecarriedoutwithnadwithoutpHadjustmentincathodechamberof acidifiedelectroplatingsludge．Theelectrokineticexperimentswereconductedunderaconstantpotential(32V)during sevendaysofEKprocess．Theselectivesequentialextraction(SSE)wasusedtodeterminethefractionationofheavy metalsintheelectroplatingsludge．Themobilityofheavy metalsinelectroplatingsludgesignificnatlyincreasedafterits acidification atthepH of4．5 nad followed the order：CrNiZnCuPb．Afterthe experimentwith acidified electroplatingsludgenadpHadjustmentatcathodechamber,theremovalefficienciesofheavymetalswere：74．02％for Zn，68．38％ ofrNi，39．22％ forCu，21．37％ ofrPb，andtheexchangeable，carbonateandsulfatefractionationsofheavy metalsininitialelectroplatingsludgewereconvertedtosolublefractionation．However,elecrtoplatingsludgeacidified treatmentandpHadjustedincathodechamberofacidifiedelectroplatingsludgerteatmentwerenotbeneficialtoimprove theremoralefficiencyofCr,theremovalefficiency ofCrdecreasedfrom 77．83％ ofconrtoltreatment