【环境工程专业】【毕业论文+开题报告+文献综述】碳纤维修饰电极在酸性溶液中对亚硝酸跟的检测.doc

（20 届） 毕业设计 碳纤维修饰电极在酸性溶液中对亚硝酸跟的检测 摘要:亚硝酸盐是一种普遍存在的化合物，主要存在于水，土壤和食品当中。它可以维持血液流动平衡，还可以在含氮氧化合物代谢中当含氧量低的情况下起到平衡代谢的作用。但是，亚硝酸盐对人体也有较大的危害，含氮亚硝基化合物作为食品添加剂和防腐剂时，能够长期残留在食品当中。人类如果经常性食用含有亚硝基化合物的食品，会导致胃癌、食道癌等重大疾病。 为了人类的健康，我们需要建立简便、灵活、准确的亚硝酸根的分析方法。电化学方法测定亚硝酸根一般是根据亚硝酸盐的氧化或还原过程来对其进行定量分析。该测定方法所使用的仪器简单、灵敏度高、检测速度快，是一种理想的检测方法。 本文采用碳纤维修饰电极来测定亚硝酸根，主要检测了碳纤维修饰电极在酸性溶液中对亚硝酸根离子的各种电化学行为。实验结果表明，修饰电极对亚硝酸根的氧化有很好的电化学响应，且存在氧化峰电流和浓度的线性关系。 关键词:Abstract Nitrite is a ubiquitous compound，existing mainly in water, soil and food products. On the one hand , It maintains the balance of blood flow，as well as playing a role in metabolic balance of nitrogen oxides when the oxygen content is low. However, on the other hand, it may do great harm to human’s health when nitrous-contained compound involves as food additive and preservative, which could long-term residue in food products, and then result in recurrent gastric cancer, esophageal cancer or some other serious diseases. Therefore, for the sake of human’s health, a simple, flexible and accurate testing approach of nitrite should be established. Among various approaches, electrochemical determination of nitrite is generally relied on quantitative analysis of oxidation or reduction process of nitrite. It is an ideal method because of its simplicity, flexibility and accuracy. This article uses modified carbon fiber electrode to test nitrite. Testing results show that modified carbon fiber electrode has a good electrochemical response to oxidation process of nitrite. Further, a linear relationship between the oxidation peak current and concentration is approved. Keywords: modified carbon fiber electrode, nitrite, electrochemical response, oxidation and reduction process 目 录 1绪论 1 1.1 亚硝酸盐概述 1 1.2 电化学分析概述 1 1.2.1 电化学分析法的特点 1 1.2.2 电化学分析法的分类 2 1.3 化学修饰电极 2 1.3.1 化学修饰电极的优点 3 1.3.2 碳纤维修饰电极的应用 3 2 实验部分 4 2.1 主要仪器和试剂 4 2.2 实验步骤 4 2.2.1 裸玻碳电极预处理 4 2.2.2 多壁碳纳米管修饰电极的制备 4 2.2.3 制备磷酸盐标准缓冲溶液 4 2.2.4 检测亚硝酸根离子 5 3 结果与分析 6 3.1 碳纤维修饰电极的电镜结果 6 3.2 碳纤维修饰电极上的亚硝酸根