偏高岭土地质聚合物的制备和力学性能研究外文文献翻译英文原文.docVIP

Colloids and Surfaces A: Physicochem. Eng. Aspects 268 (2005) 1–6 Synthesis and mechanical properties of metakaolinite-based geopolymer Hongling Wanga,b,?, Haihong Lia, Fengyuan Yana aStateKeyLaboratoryofSolidLubrication,LanzhouInstituteofChemicalPhysics, ChineseAcademyofSciences,Lanzhou730000,China bGraduateSchooloftheChineseAcademyofSciences,Beijing100864,China Received 6 July 2004; received in revised form 7 December 2004; accepted 22 January 2005 Available online 12 September 2005 Abstract Metakaolinite-based geopolymer has been synthesized at about 20 ? and sodium silicate solution. The reaction product was compressed at 4MPa in mould and then cured at 65 C from metakaolinite under activation of NaOH solution (4–12mol/L) C in oven for 10h. Flexural ? strength, compressive strength and apparent density of the material were systematically measured. The effect of concentration of NaOH solution on the mechanical and chemical properties of the geopolymer was investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared spectrometry (IR). Results show ?exural strength, compressive strength and apparent density of the geopolymer increase along with the increase of concentration of NaOH solution within 4–12mol/L. Storage time in air has slight effect on ?exural strength while almost has no effect on the compressive strength and apparent density. XRD and IR analyses indicate the geopolymer material is composed of amorphous phase and semi-crystalline phase, containing adsorbed atmospheric water and small amount of inert ingredients originated from the metakaolinite. Content of the amorphous phase in the geopolymer increased along with the increase of NaOH concentration. SEM results show the synthesized geopolymer maintained layer structure of metakaolinite particulates, thus it was thought that the geopolymeric reaction mainly occurred at the surface of the micro?ake of metakaolinite particulates. But this presumption need