珠江河口水体有机磷农药的含量与季节变化.pdfVIP

中国环境科学 2013,33(2) ：312~318 China Environmental Science 珠江河口水体有机磷农药的含量与季节变化 * 周 慜,石 雷 ,李取生,杨 璇 (暨南大学环境工程系,水土环境毒害性污染物防治与生物修复广东省高校重 点实验室,广东 广州 510632) 摘要：定期采集珠江口地区 3 条河涌的水样,分析 9 种有机磷农药(OPPs)含量及其时空变化规律.监测期间,9 种 OPPs 中有7 种被检出,检出 率由高到低依次为: 甲拌磷(97.5%) 、敌敌畏(80.0%) 、乙拌磷(77.5%) 、灭线磷(15.0%) 、乐果(10.0%) 、甲基对硫磷(5.0%) 、毒死稗(5.0%). ∑OPPs 浓度为 0.46~43.60µg/L,平均为 7.25µg/L,与其他地区相比处于较高的污染水平.珠江口有机磷农药的污染状况受季节影响十分显著. 从丰水期至枯水期 ,沙湾水道、蕉门水道、万顷沙∑OPPs 均值分别从 7.82µg/L 降至 2.24µg/L,10.58µg/L 降至 6.46µg/L,13.08µg/L 降至 3.32µg/L. 3 条水道水质受农田面积、种植类型等因素的影响,OPPs 污染状况和组成有较大的差异. 关键词：有机磷农药污染；季节变化；珠江三角洲 中图分类号：X522 文献标识码：A 文章编号：1000-6923(2013)02-0312-07 The concentration and seasonal variation of organophosphorus pesticide residues in the Pearl River estuary. ZHOU * Min, SHI Lei , LI Qu-sheng,YANG Xuan (Key Laboratory of Water/Soil Toxic Pollutants Control and Bioremediation, Department of Education of Guangdong Province, Department of Environmental Engineering, Jinan University, Guangzhou 510632, China). China Environmental Science, 2013,33(2)：312~318 Abstract ：Water samples were periodically collected from three rivers in the Pearl River Estuary. The concentrations of 9 organophosphorus pesticide residues (OPPs) and their spatial-temporal dynamics were investigated. The results show that 7 OPPs were found and the detected rate of OPPs in water samples was in the order as follows: phorate (97.5%), diehlorvos (80.0%), disulfoton (77.5%), ethoprop ( 15.0%), dimethoate (10.0%), methyl parathion (5.0%), chlorpyrifos (5.0%); The concentrations of the total organophosphorus (∑OPPs) were in the range of 0.46~43.60μg/L, with average concentration of 7.25μg/L ; Comparing with the reference data of other areas, the water body in this regions w