我国青霉素钾盐特征VOCs的挥发损失估算.pdfVIP

中国环境科学 2012,32(12) ：2134~2139 China Environmental Science 我国青霉素钾盐特征 VOCs 的挥发损失估算 * 沈伯雄 ,胡国丽,李冬倩,王 凯 (南开大学环境科学与工程学院,天津 300071) 摘要：针对我国典型制药行业——青霉素钾盐生产工艺过程中,特征 VOCs 的排污节点分 ,利用大量调研数据、物料衡算和经验公式,估 算了生产每吨青霉素钾盐各排污节点 VOCs 的挥发量,结合我国近年来青霉素钾盐产量情况,估算出其总排放量.结果表明,在青霉素钾盐生 产过程中,特征 VOCs 为醋酸丁酯和丁醇,主要产生在提取阶段、精制阶段以及储罐呼吸过程中,并且在我国,生产单位质量青霉素钾盐醋酸 丁酯和丁醇的挥发量大约为 20.49kg/t 和 12.93kg/t.该研究可为制药行业青霉素钾盐生产工艺过程中 VOCs 的管理与控制提供科学依据. 关键词：青霉素钾盐；醋酸丁酯；丁醇；挥发损失；估算 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2012)12-2134-06 Estimation of the volatilization amount of typical VOCs for production of potassium penicillin salt in China. SHEN * Bo-xiong , HU guo-li , LI Dong-qian, WANG Kai (College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China). China Environmental Science, 2012,32(12) ：2134~2139 Abstract ：Volatilization amount of typical VOCs for the production potassium penicillin salt per ton in China is estimated on the basis of emission nodes analysis, investigate data, and empiric formulas. According to the total production of potassium penicillin salt in China in recent years, the total volatilization of VOCs is also suggested. It shows that the typical VOCs are butyl acetate and butanol for the production potassium penicillin salt, which are mainly discharged from extraction, refining and tank breathing process. The volatilization of butyl acetate and butanol are about 20.49kg/t and 12.93kg/t respectively for one ton potassium penicillin salt. In recent years, the annual typical VOCs volatilization of potassium penicillin salt is becoming greater. The estimation methods and emission inventory will do help for the environmental management and emission reduction control of VOCs for potassium