用于柴油脱硫离子液体的再生研究（毕业设计）.doc

摘 要 离子液体具有熔点低，蒸气压低，电化学窗口大，酸性可调节及良好的溶解度、黏度和密度等特点，在有机反应中不但可以代替普通有机溶剂，，[Bmim]FeCl4)，研究了离子液体的黏度和电导率随温度的变化，并对它们进行拟合。采用循环伏安法研究了Fe(III)/Fe(II)在[Bmim]FeCl4Fe3+扩散控制的可逆过程，但是发现Fe3+没有完全还原为Fe2+，40℃时转移的电子数仅为0.3，Fe(III)在[Bmim]FeCl4Arrhenius公式，kJ/mol，进一步的电解表明合适的电解电压为-1.6V，电流密度随温度的升高而增加，乙二醇不能有效提高铁基离子液体的电导率。 关键词：[Bmim]FeCl4，离子液体，电解，循环伏安法，电化学行为 Abstract Ionic liquids have properties of low melting point,low vapor pressure,wide electrochemical window,adjustable acidity,strong solubility,high viscosity and so on.Ionic liquids (ILs) have been applied in many fields of industry process and science research in world in recent years.With increasing application,synthesis of ILs andphysicochemical and thermo physical properties of ILs are required. This article used [Bmim]FeCl4 made by us,the changing of Ionic liquids viscosity and conductivity with temperature were studied and fitted.The electrochemical behaviors of Fe(Ⅲ)/Fe(Ⅱ) redox couple in [Bmim]FeCl4 system were investigated by cycle voltammetry.the results showed that the process was a diffusion-controlled reversible process.But that did not fully change Fe3+ to Fe2+,at 40℃ the number of electrons transferred only 0.3.The relationship between diffusion co-efficient and temperature agreed well with the Arrhenius equation.Reduction peak current increases with increasing temperature ,the diffusion activation energy of Fe(III) in [Bmim]FeCl4 system was 23.288kJ/mol.Further electrolysis showed that the proper electrolytic voltage was -1.6V and current density increased with increasing temperature,Ethylene glycol can not improve the conductivity of iron-based ionic liquids. Key words：[Bmim]FeCl4Ionic liquid, Electrolysis,Cyclic voltammetry electrochemical behavior 目 录 第一章 前言 1 1.1 绪论 1 1.2 柴油加氢脱硫技术 2 1.3 离子液体脱硫技术及离子液体的简介 2 1.4 离子液体的合成 4 1.5 离子液体的性质 5 1.5.1 熔点 5 1.5.2 热稳定性 5 1.5.3 黏度 6 1.5.4 密度 6 1.5.5 导电性 6 1.5.6 电化学窗口 6 1.6 离子液体的特点 7 1.7 离子液体的应用 7 1.7.1 离子液体在化学反应中的应用 7 1.7.2 离子液体在分离纯化的应用 8 1.7.3 离子液体在电化学中的应用 9 1.7.4 咪唑类离子液体合成及其应用研究 9