以SiO2为基质含N类复合分离材料研究.pdfVIP

以Si0i为基质的含N类复合分离材料的研究 摘要 达到了预期研究目的，在硅胶的表面通过结合有化学反应活性的活性膜与聚乙烯亚 胺(PEI)树脂结合，取得了成功。并且通过性能测试证明，本实验制备的复合SiO,/PEI 树脂复合分离材料有着优良的吸附性能和最小的中间体环境污染，为以后的投入工 业生产奠定了良好的理论基础少、一 关键词:硅胶 聚乙烯亚胺 复合分离材料 以sio，为基质的含N类复合分离材料的研究 摘要 Abstract Organicnitrogenouspolymersbelongtoseparatingmaterialsthathavethe characterofchelatingbondswithsomemetalions.Becauseoftheirhighadsorbing capacity,especiallyoftheiradsorbingselectivitytodear,rare,andheavymetalions,they areofcomprehensivelyapplicablevalueinanalysis,metallurgy,watertreatmentandocean sourceutilization.Usingthesilicaasasupportandusingthekindsoforganiccompounds toformachoromatographiccolumnpackingmaterialsareanewwaytoraisethe applicableefficiencyoforganicnitrogenouspolymerandtoopenupanrouteofthefast andconvenientdynamicselectiveseparation. Thispaperworkedonthenitrogenouscompositeseparatingmaterialbasedonsilica. Itmainlyincludesfiveparts: 1.DevelopmentofIonSeparatingPolymerMaterials; 2.studyonthetechniqueofsurfacehydrationforporoussilica; 3.thesynthesisandcharacterizationoftheactivefilm/silicacompositematerial withitsendgroupcontainingbromine; 4.PreparationofNitrogenousPolymericCompositeSeparatingFilmBasedon Silica; 5.adsorptionpropertyinvestigationofthenitrogenouscompositeseparatingmaterial basedonsilica. Agreatnumberofdomesticandaboardliteratureweresummarizedinthepaper. Thispaperreviewedtheprogressofstudyonabsorptionprocessofmetalionsandthe studyonheavymetalchelatingagents.ThepreparationofPEI(poly(ethyleneimine))/Si02 compositeseparatingmaterialwasanalyzed.Thestudyonsurfacetreatmentofporous silicawasreported.Andthechangesofcontentofhydroxy(-OH)andofhydrophilicity afterthetretmentbythemeansofchemistry,microwave,plasma,etcwereinterpreted.The structureofC=ConsurfacewasstudiedbyXPS.Theactivefilm/silicacompositemat