改性淀粉DAS作为纤维素纤维防皱整理剂的研究.pdfVIP

摘 要 本论文通过对原有纤维素纤维防皱整理剂的对比和分析，并指出其各自的优 点和缺点，开发一种无甲醛树脂整理剂一二醛淀粉 (DAS)。试验讨论了二醛淀 粉的水解条件，及其对织物整理的影响。按传统的整理工艺，讨论了焙烘温度和 时间对织物整理的影响。在催化剂方面，详细讨论了金属盐及其混合盐催化剂， 分析了这类催化剂对整理后织物折皱回复角、白度和断裂强度的影响，通过正交 试验找出最佳工艺条件。龟于整理后织物白度的下降和断裂强力的损伤，本. 选用了乙二醇和甘油作为改善织物白度和强力的添加剂。同时还开发了有机酸和 金属盐复配催化剂，分析了这种催化剂及其工艺条件对织物整理的影响}r*课题 还讨论了柔软剂对织物整理效果的影oral.娜，将二醛淀粉整理剂和常用的树脂 整理剂的整理效果力口以比较，并，。试其水洗牢度歹通过以上研究和分析，确定二 醛淀粉整理剂是一种整理效果较好的无甲醛整理剂。 关键词: =Mve丫 无甲醛 防皱整理 纤维素纤维了 水解 ABSTRACT Bycomparingwithandanalyzingtheoldcellulosefabricswrinkle resistantfinishingagent,indicatingtheiradvantageandshortcoming,this subjectexploitsanon-formaldehydecross-linkingagent一Dialdehyde Starch (DAS).TheyhavebeendiscussedofconditionsforDAS hydrolysisandtheireffectonfabricsfinishing.Accordingtotraditional finishingtechnology,Curingtemperatureandtimeeffectsonfabrics finishinghavebeenstudied.Onthecatalystsrespects,metalsaltandtheir mixedsalthavebeendiscussed.TheireffectsonWRA 、whitenessand tensilestrengthoffinishingfabricshavebeenanalyzed.Theoptimum finishingprocessconditionshavebeendetermined妙 orthogonal experimentdesignation.Duetothedropinthefabricswhitenessand tensilestrength,Ethyleneglycolandglycerinhavebeenchoosenas additivesinamelioratingwhitenessandtensilestrengthofthefabrics.At thesametime，organicacidandmetalsaltbuiltcatalysthasbeen exploited.Theeffectofthiscatalystanditsprocessconditiononthe fabricsfinishinghavebeenanalyzed.Thesoftenereffectonthefabrics finishalsohasbeendiscussedinthissubject.Atlast，theHDASfinishing resulthasbeencomparedwitholdwrinkleresistantfinishingagent，and washingfastnessalsohasbeenestimated B‘ytheabovestudiedand analyzed，HDASfinishingagentisbeenestimatedasanon-formaldehyde wrinkleresistantfinishingagentpossessingbetterwrinkleresistant finishingresult. KEYWORDS Dialdehyde Non-formaldehyde WrinkleResistant Finishing