材料加工形态学5-1.聚合物加工结构性能-静态混合器.pptVIP

共混物－加工－相形态-----混炼器共混 Contents 混炼器的种类及结构 混炼器中聚合物结构与性能 Mixer Accessories Miniature mixers Miniature mixers Pan milling Analysis of the Influence on the Stream Flow Conditions 两种聚合物在熔融加工过程中的形态发展 Morphology development during melt blending Mechanism for inversion of phase continuity Mechanism for inversion of phase continuity (a) Sheets of major phase are pulled off the softening pellets near the major component’s transition temperature. (b) The sheets form lamellar domains inside the minor phase (c) break up into irregular pieces of different sizes (d) inversion of phase continuity occurs through coalescence of the major phase and inclusion of the minor phase. During the inversion process, small particles of major phase may be trapped inside the minor phase. Phase Inversion PA6,6/PS 混炼器加工的聚合物结构与性能 分散相尺寸的控制 Coalescence and interfacial tension 特殊设备中的混合形态 Pan-Milling Miniature mixers 无机填料对形态的影响 Nanoclay Carbon Nanotube 加工的影响因素 Time Temperature……. Quiescent Annealing 混炼器加工的聚合物结构与性能 分散相尺寸的控制 Coalescence and interfacial tension 特殊设备中的混合形态 无机填料对形态的影响 加工的影响因素 coalescence and interfacial tension in controlling dispersed phase size reduction coalescence and interfacial tension in controlling dispersed phase size reduction how much compatibilizers might be in the interface coalescence and interfacial tension in controlling dispersed phase size reduction coalescence and interfacial tension in controlling dispersed phase size reduction * * Blend-Processing-Phase Morphology -------Kneading in the Mixer 轧辊转子、 凸轮转子、 班布里转子 西哥玛转子 Loading chutes (加料槽) - for quick and reproducible loading of free-flowing substances like PVC dry blends Pressure rams （压柱） - for loading materials that are sensitive to heat and/or pressure Sealing cover （密封盖） - for running tests under inert gas Metering pumps / burettes （计量泵） - for titrating liquids into the mixer Solenoid valve unit（螺线管阀） - for controlled cooling of electrically heated measuring mixers Circul