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本论文得到 国家科技攻关计划资助 （项目编号：2006BAF02A24） 特此鸣谢 西南科技大学　　材料科学与工程学院 2008年4月11日 摘　　要 本文分别通过单滴法、双滴法和尿素法三种不同的方法合成了层状双金属氢氧化物，通过对比三种方法合成的层状双金属氢氧化物的XRD图以及SEM图得出采用双滴法合成的MgAl-LDH比采用单滴法合成的结晶度好，而通过尿素法合成的层状双金属氢氧化物的晶相单一，结构完整结晶程度好结果表明：减水剂插层MgAl-LDH层间后，XRD特征衍射峰向小角度移动，层间距增大；红外图谱在H2O和Na2CO3中研究了缓释性能机理，结果表明产物具有的缓释性能，且释放速率较大的初期符合一级动力学方程，其缓释机理主要为客体阴离子与介质中CO32-的离子交换过程。水泥净浆流动度测试表明，商品系减水剂相比，。水泥净浆流动度测试表明Layered double hydroxides was synthesized by urea method, low supersaturation, and high supersaturation.The best method was found by constrasting XRD and SEM of three methods. A novel controlled-release superplasticizer with feature of lower flowability loss of cement pastes was synthesized by intercalating superplasticizer molecule into the galleries of layered double hydroxide-like host materials (MgAl-LDH) by calcine-recovering method and co-precipitation techniques (urea method). The resulting materials characterization was carried out using XRD, SEM, DSC-TG, IR, UV-Vis, Zeta potential, flowability of cement paste, specific surface area, laser particle size and EDS. 　　The results of XRD and FT-IR indicate that the primary XRD peak of MgAl-LDH intercalated by superplasticizer molecule shifts towards low angle value and the interlayer spaces expand, which can be attributed to insert organic superplasticizer molecule into the interlayer space of the host materials. The FTIR spectroscopy of controlled release superplasticizer shows the new absorption peaks of superplasticizer. Release property,release course and release mechanism of controlled-release naphthalene-based superplasticizer were studied in pure H2O and Na2CO3 solution and the results indicate that the products had controlled release property and the primitive release process accords with the first-order kinetics equation.Release mechanism of sample was actually an anions exchange process between the CO32- and superplasticizers. Cement paste fluidity test was show the product had controlled release property. Release property of controlle