丙烯酸丙烯酰胺复合吸水材料的制备与吸水性能的测定.docxVIP

探究性化学实验报告学 院： 化学化工学院 专 业：高分子材料与工程学 号：姓 名： 指导老师： 丙烯酸/丙烯酰胺复合吸水材料的制备与吸水性能的测定摘　要:　水溶液聚合法合成了聚丙烯酸-丙烯酰胺P(AA-AM)。系统研究不同单体配比、单体总浓度等条件对P(AA-AM)吸湿性能的影响。正交实验确定最佳反应条件,其最高吸湿率达0.979g/g。吸湿实验结果发现P(AA-AM)共聚物的吸湿性能优于其相应的均聚物和传统的无机吸湿材料硅胶和分子筛。丙烯酸(AA)和丙烯酰胺(AM)的共聚物是一类用途广泛的多功能高分子化合物。如调整AM与AA的单体比例和反应条件,可制备不同结构和不同分子量的共聚物,以适应作为絮凝剂、石油开采的驱油剂及阻垢剂等要求。因丙烯酸和丙烯酰胺各自含羧酸基(—COOH)和酰胺基(—CONH)这样的强吸湿基团,故被作为有机高分子吸湿材料的重要一类。本文系统地研究共聚单体配比对P(AA-AM)吸湿性能的影响,为选择最佳工艺条件提供了依据。关键词:　P(AA-AM);吸湿;收缩率;共聚ABSTRACTAqueous solution polymerization synthesized poly acrylic acid-acrylamide P (AA - AM). System research different ratio of monomers, total monomer concentration of conditions on the P (AA - AM) the influence of moisture absorption performance. Orthogonal experiment the optimum reaction conditions, the maximum moisture absorption rate of 1.05 g/g. Hygroscopic experimental results found that P (AA - AM) copolymer of moisture absorption performance is better than its corresponding homopolymer and traditional inorganic hygroscopic material silica gel and molecular sieve. Acrylic acid (AA) and acrylamide (AM) copolymer is a kind of widely used multi-functional polymer compound. Such as adjusting AM and AA monomer ratio and reaction conditions, can be prepared by different structure and different molecular weight of the copolymer, so as to adapt to as flocculating agent, oil production of oil displacement agent and scale inhibitor and requirements. Because of the acrylic acid and acrylamide each containing acid base (- COOH) and amide group (- CONH) such a strong suction wet group, so be as organic polymer hygroscopic material of important. This paper systematically research comonomer ratio, monomer concentration and polymerization conditions on the P (AA - AM) the influence of moisture absorption performance, choose the best process conditions provide the basis.Key words: P (AA - AM);Moisture absorption, Shrinkage; copolymerization 引言空气湿度是与人们生活和生产密切相关的环境参数。长期在潮湿的环境中生活和工作,身体会受到“湿”的侵袭热平衡被破坏不仅影响人体健康，且会降低工作效率。湿度对产品生产过程、产品质量和保存期