对XRD分析有参考作用.pdfVIP

Available online at ScienceDirect Journal of the European Ceramic Society 34 (2014) 1303–1310 Effect of valeric acid on the agglomeration of zirconia particles and effects of the sintering temperature on the strut wall thickness of particle-stabilized foam Rizwan Ahmad a,b , Jang-Hoon Ha a , In-Hyuck Song a,b,∗ a Engineering Ceramic Department, Korea Institute of Materials Science, 797 Changwondaero, Seongsan-gu, Changwon, Gyeongnam, 642-831, Republic of Korea b University of Science Technology (UST), 217 Gajeong-ro, Yuseong-gu, Daejeon, 305-350, Republic of Korea Received 16 August 2013; received in revised form 5 November 2013; accepted 10 November 2013 Available online 2 December 2013 Abstract Highly porous zirconia ceramics were prepared utilizing a particle-stabilized direct foaming technique in which the hydrophilic characteristic of zirconia particles was altered by the in situ adsorption of valeric acid on its surface. These surface modified zirconia particles are irreversibility adsorbed at the air/water interface and create an armor coating around the bubbles to stabilize them. In this study, the foamability and stability of zirconia foam were investigated by varying the valeric acid concentration, and zirconia foam with a foam volume of approximately four times the colloidal system volume was successfully prepared. The sintered foam has cell size ranging from 50 to 150 m and the pore structure was characterized by mercury porosimetry. The effects of the sintering temperature on the grain size, strut wall thickness, and tetragonal phase were studied and corre